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Here, this study reports a binding\u2010assisted strategy for the selective in\u2010pore growth of MOF\u2010808 within polyacrylonitrile (PAN)\/polyvinyl pyrrolidone (PVP) hollow fibers at 30 \u00b0C. Alkaline hydrolysis of PAN introduces anchoring sites for zirconium clusters, while ethanol\u2010assisted solvation promotes MOF crystallization under ambient conditions. The spatial distribution and surface charge of hydrolyzed PVP suppress MOF nucleation on the outer surface, enabling uniform in\u2010pore growth with 34 wt.% loading and &gt; 99% retention after ultrasonication. Post\u2010synthetic functionalization with ethylenediaminetetraacetic acid (EDTA) imparts a strong affinity for Pb\n                    <jats:sup>2+<\/jats:sup>\n                    , Ni\n                    <jats:sup>2+<\/jats:sup>\n                    , and Co\n                    <jats:sup>2+<\/jats:sup>\n                    ions. The EDTA\u2010modified composite exhibits a 2.5\u2010fold increase in Pb\n                    <jats:sup>2+<\/jats:sup>\n                    adsorption kinetics compared to physically blended counterparts. A modularized 105 cm fiber unit effectively treats 1 L of a mixed\u2010metal solution (10 ppm each), underscoring the scalability and process compatibility of this approach. This work demonstrates a mild, scalable, and leaching\u2010resistant route for fabricating MOF\u2010polymer hybrid sorbents through spatially controlled in\u2010pore crystallization, offering a robust platform for water treatment and metal recovery applications.\n                  <\/jats:p>","DOI":"10.1002\/advs.202511437","type":"journal-article","created":{"date-parts":[[2025,11,7]],"date-time":"2025-11-07T12:10:16Z","timestamp":1762517416000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Scalable Hollow Fiber Adsorbents for Metal Ion Recovery via Selective In\u2010Pore MOF\u2010808 Growth under Aqueous Conditions"],"prefix":"10.1002","volume":"13","author":[{"given":"Ho Jun","family":"Lee","sequence":"first","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Sogang University  Seoul 04107 Republic of 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