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Here, a rational design of 3D layered integrated electrodes is introduced for Pd\u2010catalysed ethanol oxidation, in which chemically grafted pyrrolic or picolinic amide linkers are employed to co\u2010anchor Pd nanoparticles on an MXene support via a \u201chand\u2010in\u2010hand\u201d molecular coordination mode. This approach leads to good directional exposure of Pd (111) crystal surfaces through tailored ligand\u2010metal\u2010support interactions, creating well\u2010defined, more efficient Pd catalytic sites; thereby, the inherent limitations of the random distribution of the palladium surface sites can be overcome. The resulting system incorporating pyrrolic ligands exhibits excellent cycling stability (up to 10\u00a0000 cycles with 97.9% capacity retention), making it one of the most efficient ethanol oxidation catalysts reported. The robust Pd immobilisation after MXene functionalisation with the pyrrolic linkers allows achieving this performance with low Pd loadings, while calculations also indicate weaker adsorption of catalyst\u2010poisoning oxidation intermediates. This new, modular approach provides a pathway to more efficient electrocatalytic systems for real\u2010world applications in ethanol fuel cells.<\/jats:p>","DOI":"10.1002\/advs.202513512","type":"journal-article","created":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T02:28:57Z","timestamp":1760408937000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Sustained and Efficient Ethanol Oxidation by Tethering Tunable N\u2010Donors Onto Integrated MXene\/Pd\u2010Electrodes"],"prefix":"10.1002","volume":"13","author":[{"given":"Zhangxin","family":"Chen","sequence":"first","affiliation":[{"name":"Zhejiang Key Laboratory for Island Green Energy and New Materials Taizhou University  Taizhou Zhejiang 318000 China"},{"name":"Yusuf Hamied Department of Chemistry University of Cambridge  Cambridge CB2 1EW UK"},{"name":"School of Pharmaceutical and Chemical Engineering Taizhou University  Taizhou Zhejiang 31800 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