{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T20:48:11Z","timestamp":1787604491836,"version":"build-2736575974"},"reference-count":36,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,2,8]],"date-time":"2026-02-08T00:00:00Z","timestamp":1770508800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,2,8]],"date-time":"2026-02-08T00:00:00Z","timestamp":1770508800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Chemiresistive gas sensors based on semiconducting metal oxides for toxic gas detection are widely explored for terrestrial applications under ambient environments, but their potential in extraterrestrial applications remains underexplored. Herein, we developed porous Cu\u2010doped SnO\n                    <jats:sub>2<\/jats:sub>\n                    microspheres, enabling high sensitivity and selectivity toward hydrogen sulfide (H\n                    <jats:sub>2<\/jats:sub>\n                    S), from the ambient air (25\u00b0C, 10\n                    <jats:sup>5<\/jats:sup>\n                    \u00a0Pa) to extreme conditions (\u221240\u00b0C, \u223c10\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>4<\/jats:sup>\n                    \u00a0Pa) designed to simulate the space\u2010like oxygen defects and cryogenic environments. Hierarchical porosity enables efficient gas diffusion across pressure regimes, and Cu\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    doping and oxygen vacancies thus enable oxygen\u2010independent chemisorption. Moreover, in situ\u2010formed chemical adsorption promotes interfacial charge transfer, which exhibits partial reversibility. The semi\u2010quantitative framework represented by a CuS kinetic proxy, combining numerical simulations based on Wolkenstein adsorption theory, finite element methods, and experimental results, reveals a dual\u2010mechanism paradigm. At ambient conditions, the oxygen\u2010adsorption\u2010driven redox reaction is dominant. In contrast, under a vacuum around 10\n                    <jats:sup>\u22124<\/jats:sup>\n                    \u00a0Pa, direct chemisorption and interfacial charge transfer primarily govern the gas adsorption responses. This study offers a generalized metal\u2010oxide platform for gas detection for future space exploration and life\u2010support monitoring systems.\n                  <\/jats:p>","DOI":"10.1002\/advs.202515684","type":"journal-article","created":{"date-parts":[[2026,2,8]],"date-time":"2026-02-08T17:56:06Z","timestamp":1770573366000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Wide\u2010Range Adaptive Metal Oxide for Hydrogen Sulfide Detection From Earth to Space\u2010Like Environments"],"prefix":"10.1002","volume":"13","author":[{"given":"Xi","family":"Chen","sequence":"first","affiliation":[{"name":"School of Integrated Circuits Huazhong University of Science and Technology  Wuhan P. R. 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