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The primary challenge for photocatalytic systems is how to optimally separate interfacial charges, while the hydrogen evolution reaction limits the selectivity of products in the photocatalytic reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    . Herein, highly stable Ag\n                    <jats:sub>44<\/jats:sub>\n                    nanoclusters (Ag\n                    <jats:sub>44<\/jats:sub>\n                    NCs) protected by thiol salt ligands are prepared with atomic\u2010level precision. The ultra\u2010small Ag\n                    <jats:sub>44<\/jats:sub>\n                    NCs shorten the distance for electrons to migrate from the bulk phase to the surface and accelerate interfacial charge transfer. Furthermore, the molecule\u2010like properties of Ag\n                    <jats:sub>44<\/jats:sub>\n                    NCs broaden the light absorption range of the semiconducting substrate, and quantum confinement rendered by Ag\n                    <jats:sub>44<\/jats:sub>\n                    NCs produces a potential well, which promotes electron aggregation and generates a long\u2010range ordered electric field to transfer electrons directionally. Since the electrostatic repulsion of positively charged Ag\n                    <jats:sub>44<\/jats:sub>\n                    NCs hinders electron transfer and proton coupling, the hydrogen evolution reaction is inhibited.\n                  <\/jats:p>","DOI":"10.1002\/advs.202516096","type":"journal-article","created":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T13:03:29Z","timestamp":1761311009000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Controlled Photocatalytic Reduction of CO\n                    <sub>2<\/sub>\n                    by Precise Atomic\u2010Level Interface Modification and Engineering of Silver Nanoclusters"],"prefix":"10.1002","volume":"13","author":[{"given":"Hangmin","family":"Xu","sequence":"first","affiliation":[{"name":"School of Mechanical Engineering, College of Environmental Science and Engineering Yangzhou University  Yangzhou 225009 P. R. 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