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However, atomic oxygen interaction with POSS polyimide results in a porous SiO\n                    <jats:sub>x<\/jats:sub>\n                    passivating layer, ultraviolet interaction results in bonding degradation, both causing the transmittance decrease in the visible light range. In this study, the atomic oxygen exposure\u2010induced transmittance decrease of POSS polyimide is explained and simulated by Rayleigh scattering. Ultrathin oxide films and ultraviolet absorbent are introduced to POSS polyimide by surface\u2010 and bulk\u2010phase modifications to improve atomic oxygen and ultraviolet resistance, which achieves \u22480\u00a0wt% mass loss upon an eight\u2010year long\u2010term atomic oxygen exposure and is deduced by molecular dynamics. The atomic oxygen exposure effect on the sheet resistance of flexible conductive indium tin oxide\u2010POSS polyimide is explained by band structure calculation. The SiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010POSS polyimide sealed triple\u2010junction GaAs thin\u2010film solar cell exhibits beginning of life (BOL) and end of life (EOL) efficiencies of 27.67% and 23.38% upon an eight\u2010year long\u2010term to atomic oxygen. The atomic oxygen reactions with polyimide\u2010based films are explained by zero\u2010 and first\u2010order reactions, and predictive formulas are created for the film mass loss and sealed solar cell performance under the long\u2010term atomic oxygen exposure. This study suggests a POSS polyimide composite as a packaging film for flexible photoelectronic devices in low Earth orbit.\n                  <\/jats:p>","DOI":"10.1002\/advs.202516383","type":"journal-article","created":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T03:40:48Z","timestamp":1765856448000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["POSS Polyimide Composite Sealed Triple\u2010Junction GaAs Thin\u2010Film Solar Cell for Long\u2010Term Low Earth Orbit Serve"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6472-7693","authenticated-orcid":false,"given":"Min","family":"Qian","sequence":"first","affiliation":[{"name":"School of Physics East China University of Science and Technology  Shanghai 200237 P. R. 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