{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:03:35Z","timestamp":1792163015214,"version":"4.4.0"},"reference-count":54,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,1,28]],"date-time":"2026-01-28T00:00:00Z","timestamp":1769558400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,1,28]],"date-time":"2026-01-28T00:00:00Z","timestamp":1769558400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Cathode\u2013solid electrolyte (SE) interfacial instability poses a major challenge for achieving stable and high\u2010power operations in all\u2010solid\u2010state batteries, which promise superior energy density, thermal stability, and safety over the current Li\u2010ion technology. For technologically important Ni\u2010rich NMCs (LiNi\n                    <jats:sub>x<\/jats:sub>\n                    Mn\n                    <jats:sub>y<\/jats:sub>\n                    Co\n                    <jats:sub>z<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    or NMCxyz; x\/y\/z: Ni\/Mn\/Co stoichiometry) paired with sulfide SEs, redox\u2010mediated instability of the SE is often blamed for rapid cathode deterioration. Here, in\u2010depth spectroscopic and electrochemical analyses of Ni\u2010rich NMCs with a promising sulfide SE reveal hitherto unrecognized electrochemical isolation of active NMC particles driven by rapid interfacial degradations, sparking accelerated capacity fading and poor thermal stability. Introducing a functionalized conductive carbon into the cathode suppresses sulfide SE degradation into reactive polysulfides that drive NMC deterioration. Consequently, NMC622 and NMC811\u2010based cells display high active material utilization, enhanced stability, attractive rate capability and thermal resilience \u2013 illustrated by 1C (1C: 160\u00a0mA\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) capacity of \u223c150\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 5C rate retention of 95% after 500 cycles with high active loading (\u226512\u00a0mg\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), and an average Coulombic efficiency of 99.8% even for high\u2010temperature cycling. This study uncovers a critical performance degradation pathway in a key cathode\u2010SE pairing and presents a scalable strategy for its in situ regulation, enabling significant performance gains.\n                  <\/jats:p>","DOI":"10.1002\/advs.202518327","type":"journal-article","created":{"date-parts":[[2026,1,28]],"date-time":"2026-01-28T10:00:22Z","timestamp":1769594422000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Mitigating Electrochemical Isolation in Ni\u2010Rich Layered Cathodes for Durable Solid\u2010State Batteries"],"prefix":"10.1002","volume":"13","author":[{"given":"Abhirup","family":"Bhadra","sequence":"first","affiliation":[{"name":"LBRI, School of Chemical Engineering UNSW Sydney  Kensington New South Wales Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maxime","family":"Brunisholz","sequence":"additional","affiliation":[{"name":"LBRI, School of Chemical 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