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This work reports a \u201cmortise\u2010tenon joint\u201d inspired non\u2010covalent interaction \u2014 \u201c\u03c0\u2010hole\u201d based halogen bond, that enables solvation structure regulation beyond traditional van der Waals force or hydrogen bond. The electrophilic \u03c0\u2010hole on the polymer skeleton engages in halogen bonding with solvents, thereby weakening their coordination with Li\n                    <jats:sup>+<\/jats:sup>\n                    to form a weakly solvated structure. Moreover, the fluorine\u2010rich skeleton participates in the formation of the electrode\u2010electrolyte interphases, achieving good anode compatibility and high\u2010voltage stability simultaneously. The resulting electrolyte exhibits high ionic conductivity (0.30 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and a Li\n                    <jats:sup>+<\/jats:sup>\n                    transference number of 0.84. Li symmetric cells stably cycle over 1000\u00a0h. The Li\/LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCM811) cell delivers discharge specific capacities of 161.0 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 500 cycles at 1C. Especially, the cell can work stably for 100 cycles at 80\u00a0\u00b0C (1C, 156.0 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Furthermore, the pouch cell achieves an energy density of 462.2\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This study demonstrates that the concept of a weakly solvated gel electrolyte based on halogen bonds provides a new approach to achieving high\u2010energy\u2010density LMBs.\n                  <\/jats:p>","DOI":"10.1002\/advs.202518448","type":"journal-article","created":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T04:17:11Z","timestamp":1763353031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Mortise\u2010Tenon Joint Inspired Weakly Solvated Gel Electrolyte Based on Halogen Bonds for High\u2010Voltage Lithium Metal Batteries"],"prefix":"10.1002","volume":"13","author":[{"given":"Shuohan","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Metal Matrix Composites School of Materials Science and Engineering Shanghai Jiao Tong University  Shanghai 200240 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