{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:23:51Z","timestamp":1786976631196,"version":"build-2736575974"},"reference-count":59,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T00:00:00Z","timestamp":1765843200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T00:00:00Z","timestamp":1765843200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Sulfide\u2010based solid electrolytes, particularly Li argyrodites, hold significant promise for practical all\u2010solid\u2010state batteries (ASSBs); however, their poor stability under humid conditions presents a critical challenge. Despite numerous efforts to address this issue, a comprehensive mechanistic understanding of moisture\u2010induced degradation remains limited. Herein, we introduce an Al and Se co\u2010substituted argyrodite, Li\n                    <jats:sub>6\u20103<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Al\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    PS\n                    <jats:sub>5\u20101.5<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Se\n                    <jats:sub>1.5<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Cl, which enhances both the Li\n                    <jats:sup>+<\/jats:sup>\n                    conductivity and air stability. The optimized composition (\n                    <jats:italic>x<\/jats:italic>\n                    = 0.05) exhibits an improved Li\n                    <jats:sup>+<\/jats:sup>\n                    conductivity of 4.91 mS\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 30\u00a0\u00b0C and a 22% conductivity reduction after dry\u2010air exposure (dew point: \u221240\u00a0\u00b0C for 5\u00a0h), compared with 3.71 mS\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a 42% decrease for the unsubstituted sample. Reduced surface degradation is validated by comprehensive experimental analyses. Complementary calculations indicate less favorable H\n                    <jats:sub>2<\/jats:sub>\n                    O adsorption and further reveal that Al and Se co\u2010substitution inhibits the rotation of P[S\n                    <jats:sub>2<\/jats:sub>\n                    SeO]\n                    <jats:sup>3\u2212<\/jats:sup>\n                    and P[S\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>3\u2212;<\/jats:sup>\n                    tetrahedra via preferential surface\u2010oriented Se\n                    <jats:sup>2\u2212<\/jats:sup>\n                    and Al\u2500O interactions, which otherwise promote H\n                    <jats:sub>2<\/jats:sub>\n                    O\u2010induced degradation, thereby minimizing moisture interactions. Finally, the improved electrochemical performance of the co\u2010substituted argyrodite is validated by its enhanced capacity retention following air exposure in NCM|Li\n                    <jats:sub>6<\/jats:sub>\n                    PS\n                    <jats:sub>5<\/jats:sub>\n                    Cl|(Li\u2010In) cells. This study highlights rotational dynamics as an overlooked mechanism underlying moisture\u2010induced degradation, and demonstrates that targeted co\u2010substitution is a viable strategy for advancing practical ASSBs.\n                  <\/jats:p>","DOI":"10.1002\/advs.202519093","type":"journal-article","created":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T11:39:34Z","timestamp":1765885174000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Improved Air Stability of Li Argyrodites Through PS\n                    <sub>4<\/sub>\n                    <sup>3\u2212<\/sup>\n                    Rotation Suppression by Al and Se Co\u2010Substitution for All\u2010Solid\u2010State Batteries"],"prefix":"10.1002","volume":"13","author":[{"given":"Juhyoun","family":"Park","sequence":"first","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Yonsei University  Seoul 03722 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jihun","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Yonsei University  Seoul 03722 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoon\u2010Seong","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Donghyeok","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Yonsei University  Seoul 03722 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minseo","family":"Jang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Yonsei University  Seoul 03722 Republic of Korea"},{"name":"Department of Battery Engineering Yonsei University  Seoul 03722 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junwoo","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Yonsei University  Seoul 03722 Republic of Korea"},{"name":"Department of Battery Engineering Yonsei University  Seoul 03722 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hae\u2010Yong","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Energy and Materials Engineering Dongguk University  30 Pildong\u2010ro 1\u2010gil, Jung\u2010gu Seoul 04620 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changhun","family":"Park","sequence":"additional","affiliation":[{"name":"LG Chem, Ltd  LG Science Park, 30, Magokjungang 10\u2010ro, Gangseo\u2010gu Seoul 07796 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeongheon","family":"Kim","sequence":"additional","affiliation":[{"name":"LG Chem, Ltd  LG Science Park, 30, Magokjungang 10\u2010ro, Gangseo\u2010gu Seoul 07796 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Habin","family":"Chung","sequence":"additional","affiliation":[{"name":"LG Chem, Ltd  LG Science Park, 30, Magokjungang 10\u2010ro, Gangseo\u2010gu Seoul 07796 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kyung\u2010Wan","family":"Nam","sequence":"additional","affiliation":[{"name":"Department of Energy and Materials Engineering Dongguk University  30 Pildong\u2010ro 1\u2010gil, Jung\u2010gu Seoul 04620 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong\u2010Hwa","family":"Seo","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0357-9508","authenticated-orcid":false,"given":"Yoon Seok","family":"Jung","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Yonsei University  Seoul 03722 Republic of Korea"},{"name":"Department of Battery Engineering Yonsei University  Seoul 03722 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,16]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0431-3"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2016.141"},{"key":"e_1_2_8_3_1","author":"Kim J. 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