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In this study, the photothermal catalytic reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to methane (CH\n                    <jats:sub>4<\/jats:sub>\n                    ) using boron\u2010doped Ni as a catalyst, focuses on enhancing product selectivity through reaction parameter optimization. Notably, addition of water vapor substantially improves both CH\n                    <jats:sub>4<\/jats:sub>\n                    yield (195.85 mmol g\u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and selectivity (80.21%), representing a significant advancement over traditional approaches. Through integrated experimental characterization and density functional theory (DFT) calculations, the underlying mechanism involving competitive adsorption dynamics is elucidated between CO\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    O molecules on the boron\u2010doped Ni surface, along with their parallel dissociation pathways. DFT calculations also confirm that boron doping upshifts the Ni d\u2010band center, strengthening CO adsorption for subsequent hydrogenation. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) measurements indicated that the reverse water\u2010gas shift (RWGS) reaction on boron\u2010doped Ni proceeded primarily via a dissociation pathway. Furthermore, the introduction of H\n                    <jats:sub>2<\/jats:sub>\n                    O enables alternative CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction mechanisms through the carboxylate and bicarbonate pathways. This study demonstrates the significant potential of boron\u2010doped Ni catalysts for enhanced CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation and provides valuable mechanistic insights into how reaction parameters influence the photothermal CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction process.\n                  <\/jats:p>","DOI":"10.1002\/advs.202519611","type":"journal-article","created":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T04:43:01Z","timestamp":1763354581000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Water Vapor\u2010Enhanced Selective Production of Methane During Photothermal CO\n                    <sub>2<\/sub>\n                    Reduction: Mechanistic Insights Into Boron\u2010Doped Nickel Catalysts"],"prefix":"10.1002","volume":"13","author":[{"given":"Cong","family":"Wan","sequence":"first","affiliation":[{"name":"Department of Chemical and Environmental Engineering University of Nottingham  Ningbo 315100 China"},{"name":"Municipal Key Laboratory of Clean Energy Technologies of Ningbo University of Nottingham Ningbo China  Ningbo 315100 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiming","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemical and Environmental Engineering University of Nottingham  Ningbo 315100 China"},{"name":"Municipal Key Laboratory of Clean Energy Technologies of Ningbo University of Nottingham Ningbo China  Ningbo 315100 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemical and Environmental Engineering University of Nottingham  Ningbo 315100 China"},{"name":"Municipal Key Laboratory of 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