{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T16:31:07Z","timestamp":1792600267205,"version":"4.5.0"},"reference-count":35,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2026,1,4]],"date-time":"2026-01-04T00:00:00Z","timestamp":1767484800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,1,4]],"date-time":"2026-01-04T00:00:00Z","timestamp":1767484800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFB3817305"],"award-info":[{"award-number":["2024YFB3817305"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFB4607600"],"award-info":[{"award-number":["2024YFB4607600"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Self\u2010assembled monolayers (SAMs) are extensively\u00a0employed as hole\u2010selective interlayers in inverted perovskite solar cells (PSCs), yet their incomplete coverage and poor molecular ordering often induce interfacial defects and exacerbate non\u2010radiative recombination. To overcome these limitations, we developed a bulky methylthio\u2010functionalized carbazole\u2010based SAM, (2\u2010(3,6\u2010bis(bis(4\u2010(methylthio)phenyl)amino)\u20109\n                    <jats:italic>H<\/jats:italic>\n                    \u2010carbazol\u20109\u2010yl)ethyl)phosphonic acid (S\u20102PACz),\u00a0and implemented a sequential co\u2010assembly strategy utilizing cysteine (Cys). In this tailored architecture, Cys is pre\u2010anchored via\u00a0 carboxyl groups, followed by the competitive adsorption of S\u20102PACz via phosphonic acid anchoring, yielding a mixed Cys\u2010S\u20102PACz monolayer. The size complementarity and cooperative anchoring facilitated denser molecular packing and improved ordering, while synergistic methylthio and thiol functionalities jointly passivated interfacial defects. Consequently, this strategy enhanced perovskite crystallization, optimized energy\u2010level alignment, and facilitated efficient hole extraction. Ultimately, PSCs incorporating Cys\u2010S\u20102PACz achieved higher power conversion efficiency, reduced recombination losses, and demonstrated superior thermal, operational, and outdoor stability compared with devices based on single\u2010component SAMs. This work establishes competitive co\u2010assembly as an effective interfacial engineering strategy, providing a scalable route to tailored SAM architectures for high\u2010performance and durable p\u2013i\u2013n PSCs.\n                  <\/jats:p>","DOI":"10.1002\/advs.202521037","type":"journal-article","created":{"date-parts":[[2026,1,5]],"date-time":"2026-01-05T05:26:17Z","timestamp":1767590777000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Tailored Monolayer Co\u2010Assembly for Enhanced Efficiency and Stability in Inverted Perovskite Solar Cells"],"prefix":"10.1002","volume":"13","author":[{"given":"Fen","family":"Xia","sequence":"first","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuwen","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolin","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Yin","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaohui","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Tu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering, Pen\u2010Tung Sah Institute of Micro\u2010Nano Science and Technology Innovation Laboratory For Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University Xiamen 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