{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T13:06:39Z","timestamp":1788872799297,"version":"build-2803163510"},"reference-count":60,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2026,1,4]],"date-time":"2026-01-04T00:00:00Z","timestamp":1767484800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,1,4]],"date-time":"2026-01-04T00:00:00Z","timestamp":1767484800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The pervasive dissolution of transition metal fluoride (TMF) cathodes presents a fundamental barrier to their application in high\u2010voltage thermal batteries and other Li\n                    <jats:sup>+<\/jats:sup>\n                    \u2010conducting systems. Herein, we report a novel selective confinement strategy inspired by ion sieving to overcome this challenge by constructing a sub\u2010nanoporous carbon interface in situ on CoF\n                    <jats:sub>2<\/jats:sub>\n                    particles. Derived from a covalent organic framework (COF), this interface features precisely defined 0.54\u00a0nm pores that exploit the size difference between Li\n                    <jats:sup>+<\/jats:sup>\n                    ions (\u223c0.15\u00a0nm) and dissolved transition metal fluoride derived complex ions (\u223c0.8\u00a0nm), effectively confining the active material while enabling unimpeded ionic conduction. This tailored design successfully suppresses cathode shuttling effect, enabling a thermal battery that delivers an exceptional discharge plateau &gt;2.5\u00a0V, a high specific capacity of 365\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and a remarkable specific energy of 882\u00a0Wh\u00a0kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 100\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Mechanism studies confirm the dissolved transition metal fluoride derived complex ions as CoCl\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    and efficient confinement of it. This work provides a general and effective interface engineering strategy for unlocking the full potential of metal fluoride cathodes in advanced energy storage.\n                  <\/jats:p>","DOI":"10.1002\/advs.202521241","type":"journal-article","created":{"date-parts":[[2026,1,5]],"date-time":"2026-01-05T05:35:34Z","timestamp":1767591334000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Selective Confinement by a COF\u2010Derived Sub\u2010Nanoporous Interface for High\u2010Performance CoF\n                    <sub>2<\/sub>\n                    Thermal Battery Cathodes"],"prefix":"10.1002","volume":"13","author":[{"given":"Mengfan","family":"Xu","sequence":"first","affiliation":[{"name":"University of Chinese Academy of Sciences  Beijing P. R. China"},{"name":"State Key Laboratory of Mesoscience and Engineering Institute of Process Engineering Chinese Academy of Sciences  Beijing P. R. 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