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Existing solutions relying on wettability engineering or bulk photothermal materials suffer from poor transparency, contamination vulnerability, or energy inefficiency. Here, we report an ultrathin (2.5\u00a0nm) MXene film self\u2010assembled at liquid\u2010liquid interfaces via Marangoni flow, achieving 82.5 % visible transparency while enabling a high photothermal conversion effect (\u0394T\u223c25.1\u00b0C \u00b1 2.9\u00b0C) under 100\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . It is due to the unique percolative MXene network formed at ultralow loading (&lt; 0.1\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), leveraging the critical percolation thresholds to reconcile ultraviolet (UV, 300\u2013400\u00a0nm) and near\u2010infrared (NIR, 700\u20132000\u00a0nm) absorption with visible transparency (82.5 %, 400\u2013700\u00a0nm), which overcomes the trade\u2010off between solar harvesting and transparency. Therefore, coupled with a silicone oil\u2010infused slippery surface, the composite coating (TPSS) exhibits rapid ice shedding (85 s at \u221220\u00b0C under 1 sun) and fog resistance (at 90 % humidity). Outdoor demonstrations (Beijing, 2.1\u00b0C) on eyewear and architectural models validate frost suppression, rapid de\u2010icing, and mechanical flexibility. This scalable, sunlight\u2010powered platform bridges transparency and icephobicity for next\u2010generation optical devices.\n                  <\/jats:p>","DOI":"10.1002\/advs.202522420","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T20:19:18Z","timestamp":1773001158000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Transparent Photothermal Slippery Surface Based on Monolayer Self\u2010Assembled MXene Film for Anti\u2010Fogging and De\u2010Icing"],"prefix":"10.1002","volume":"13","author":[{"given":"Xiao","family":"Han","sequence":"first","affiliation":[{"name":"State Key Laboratory of Bioinspired Interfacial Materials Science Bioinspired Science Innovation Center Hangzhou International Innovation Institute Beihang University  Hangzhou China"},{"name":"State Key Laboratory of Bioinspired Interfacial Materials Science School of Chemistry Beihang University  Beijing 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