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Among various catalyst designs, inverse catalysts have attracted growing interest due to their unique structural advantages. However, the performance of inverse catalysts, such as ZrO\n                    <jats:sub>2<\/jats:sub>\n                    \/Cu, is hindered by their hydrophilic nature, while the systematic investigations into their surface wettability remain rare. In this study, we report a non\u2010destructive hydrophobic modification strategy for ZrO\n                    <jats:sub>2<\/jats:sub>\n                    \/Cu catalyst through physical mixing with polydivinylbenzene (PDVB). The optimized ZrO\n                    <jats:sub>2<\/jats:sub>\n                    \/Cu\u2010PDVB (1:1 mass ratio) catalyst achieves a methanol space\u2010time yield of 920.10 mg\n                    <jats:sub>CH3OH<\/jats:sub>\n                    \u00a0g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    under mild conditions, outperforming the unmodified catalyst by 30%. Additionally, the optimized catalyst also demonstrates outstanding 200\u00a0h thermal stability. In situ DRIFTS and related analyses reveal that the PDVB effectively promotes water desorption and diffusion, alleviating its negative impact on the rate\u2010determining step of formate hydrogenation. This also preserves the size, metallic state of Cu particles, and the abundance of oxygen vacancies, crucial for maintaining the active ZrO\n                    <jats:sub>x<\/jats:sub>\n                    \u2010Cu interface. This work presents a simple, scalable method for adjusting the local microenvironment of inverse catalysts, highlighting the critical yet underexplored role of hydrophobic surface engineering in optimizing water\u2010sensitive catalytic systems.\n                  <\/jats:p>","DOI":"10.1002\/advs.202523915","type":"journal-article","created":{"date-parts":[[2026,2,15]],"date-time":"2026-02-15T13:22:01Z","timestamp":1771161721000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Non\u2010Destructive Hydrophobic Engineering of Inverse Catalysts for Methanol Synthesis from CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"13","author":[{"given":"Dingran","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Clean Energy Utilization Zhejiang University  Hangzhou P. R. 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