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However, achieving both robust adhesion and rapid on\u2010demand detachment in aquatic environments remains a critical challenge. Inspired by the diving bell spider, we propose a design strategy based on heterogeneous wettability surfaces to achieve switchable adhesion between two surfaces. The heterogeneous wettability surface design confines the oil phase within air cavities formed in superhydrophobic (lipophilic) regions, thereby creating annular oil rings, which establish stable oil\/water interfaces that spatially isolate the internal water bridge from the external aquatic environment. The Laplace pressure difference generated at the oil\/water interfaces induces robust adhesion between surfaces. In addition, the adhesion strength can be linearly enhanced by constructing multiple, uniformly arranged oil\/water interfaces. Rapid on\u2010demand separation can also be achieved through controlled electrolysis of the internal water bridge by applying voltage between the surfaces. Finally, we demonstrate the practical applicability of this adhesive by integrating it into an unmanned underwater vehicle (UUV) for efficient underwater anchoring and ship\u2010hull hitchhiking, highlighting its broad application potential in underwater engineering scenarios.<\/jats:p>","DOI":"10.1002\/advs.202524235","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T11:25:17Z","timestamp":1772969117000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Heterogeneous Wettability\u2010Based Construction of Two\u2010Phase Interfaces for Underwater Reversible Adhesion"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-9158-1315","authenticated-orcid":false,"given":"Xiaokai","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of High\u2010performance Precision Manufacturing Dalian University of Technology  Dalian P. R. 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