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We designed and synthesized an organic, phosphorescent di\u2010\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butyl\u2010carbazole dibenzophenazine chromophore,\n                    <jats:bold>11\u2010DTCz\u2010BP<\/jats:bold>\n                    , with an appropriate size for a tight hand\u2010to\u2010glove fit into the 1D pore channels of MIL\u201068(In). MOF particles are synthesized, and homogeneous films are prepared on Au\u2010substrates through electrochemical deposition. The steric demand of\n                    <jats:bold>11\u2010DTz\u2010BP<\/jats:bold>\n                    yields a crystallographic ordered confinement inside the pores of MIL\u201068(In), proven by XRD and DFT calculations. Through this approach, it was possible to obtain controlled packing of the chromophore and lower emission quenching factors. Detailed spectroscopic analysis was performed using (cryo)fluorescence spectroscopy on powders and thin films. We consider F\u00f6rster Resonance Energy Transfer (FRET) as a process of energy transfer between the pore walls of MIL\u201068 and\n                    <jats:bold>11\u2010DTCz\u2010BP<\/jats:bold>\n                    . The aggregation control leads to a quantum yield enhancement, while FRET enables long lifetimes of phosphorescence at room\u2010temperature.\n                  <\/jats:p>","DOI":"10.1002\/advs.202600068","type":"journal-article","created":{"date-parts":[[2026,3,15]],"date-time":"2026-03-15T18:43:43Z","timestamp":1773600223000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Enhanced Energy Transfer from a Metal\u2013Organic Framework to a Highly Confined Organic Phosphorescent Dye"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8049-2380","authenticated-orcid":false,"given":"Bahram","family":"Hosseini Monjezi","sequence":"first","affiliation":[{"name":"Institute of Functional Interfaces (IFG) Karlsruhe Institute of Technology (KIT)  Karlsruhe Germany"},{"name":"Institute for Nuclear Waste Disposal (INE) Karlsruhe Institute of Technology (KIT)  Karlsruhe 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