{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T10:58:20Z","timestamp":1787223500508,"version":"build-2736575974"},"reference-count":59,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T00:00:00Z","timestamp":1776297600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T00:00:00Z","timestamp":1776297600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Lithium\u2010sulfur (Li\u2010S) batteries offer a high theoretical specific energy of 2600\u00a0Wh\u00a0kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    , yet commercialization remains limited by poor sulfur conductivity and structural instability of sulfur electrodes due to polysulfide (Li\u2010PS) dissolution and shuttling. Here, a sulfonated zirconium\u2010based metal organic polyhedron (SMOP) is introduced as a molecularly dispersible additive for nanoscale interfacial engineering at 3\u00a0wt.% in the sulfur\u2013carbon composite. Two placement modes are implemented, where SMOP is assembled as a conformal interfacial coating on sulfur\u2010loaded hollow carbon spheres (SMOP\u2010S\u2010HCS), whereas SMOP is introduced by co\u2010deposition\/physical blending with Ketjen black (SMOP\u2010S\u2010KB), producing a dispersed\/buried distribution without a defined surface layer. SMOP\u2010S\u2010HCS delivers a low shuttle charge (\n                    <jats:italic>\n                      Q\n                      <jats:sub>PS<\/jats:sub>\n                    <\/jats:italic>\n                    ) of 54.0\u00a0mAh\u00a0g\n                    <jats:sub>S<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    , whereas SMOP\u2010S\u2010KB exhibits approximately 1.7\u2010fold higher\n                    <jats:italic>\n                      Q\n                      <jats:sub>PS<\/jats:sub>\n                    <\/jats:italic>\n                    despite identical SMOP loading during the Li\u2010PS shuttle current measurement. SMOP\u2010S\u2010HCS delivers robust rate capability with discharge capacity ranging from \u223c1500 to \u223c800\u00a0mAh\u00a0g\n                    <jats:sub>S<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    from 0.05 to 2C and sustained discharge capacity of 850\u00a0mAh\u00a0g\n                    <jats:sub>S<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 400 cycles at 0.3C. Ex situ sulfur K\u2010edge XAS confirms the effectiveness of SMOP functional barrier against Li\u2010PS shuttling by probing more reversible sulfur speciation and reduced oxidized sulfur buildup during cycling.\n                  <\/jats:p>","DOI":"10.1002\/advs.75347","type":"journal-article","created":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T19:25:42Z","timestamp":1776367542000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Interfacial Polysulfide Confinement via Spatially Controlled Sulfonated Metal\u2013Organic Polyhedra Coatings in Lithium\u2013Sulfur Batteries"],"prefix":"10.1002","volume":"13","author":[{"given":"Soyeon","family":"Ko","sequence":"first","affiliation":[{"name":"Chemical Engineering Fulton Schools of Engineering Arizona State University  Tempe Arizona 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