{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T05:22:33Z","timestamp":1790572953753,"version":"4.1.0"},"reference-count":67,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2026,5,5]],"date-time":"2026-05-05T00:00:00Z","timestamp":1777939200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,5,5]],"date-time":"2026-05-05T00:00:00Z","timestamp":1777939200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["2106158"],"award-info":[{"award-number":["2106158"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["2023179"],"award-info":[{"award-number":["2023179"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Slide\u2010ring network (SRN) hydrogels derived from ring\u2010crosslinked polyrotaxanes exhibit exceptional mechanical properties attributable to a pulley effect, whereby mobile\u2010ring crosslinks redistribute tension under deformation through a slip\u2010link mechanism. However, SRN hydrogels weaken severely upon swelling in water, limiting their utility at high water content (90 wt.%). Here, two distinct physical slip\u2010link mechanisms are combined in a highly entangled slide\u2010ring double network (HESRDN) hydrogel: the pulley effect of a polyrotaxane slide\u2010ring network and the entangled chains of a sparsely cross\u2010linked polyacrylamide network. HESRDN is prepared by photopolymerization of acrylamide\/\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    '\u2010methylenebis(acrylamide) within a partially swollen slide\u2010ring hydrogel. The dual slip\u2010link architecture synergistically strengthens and toughens the hydrogel far beyond the sum of the component networks, yielding high work of fracture (1275\u00a0kJm\n                    <jats:sup>\u22123<\/jats:sup>\n                    ), toughness (2020\u00a0Jm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), and near\u2010complete reversibility (99.7%) at 91\u00a0wt.% water. HESRDN withstands continuous friction for over 12\u00a0h without rupture, compared to minutes for the SRN and 5\u00a0h for the HEN component networks, reflecting the unique capacity of the dual slip\u2010link architecture to delocalize and redistribute stress under sustained mechanical\u00a0loading.\n                  <\/jats:p>","DOI":"10.1002\/advs.75525","type":"journal-article","created":{"date-parts":[[2026,5,5]],"date-time":"2026-05-05T19:50:56Z","timestamp":1778010656000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Synergistic Dual Slip\u2010Link Toughening of a Water\u2010Rich Double Network Hydrogel Combining Slide\u2010Ring and Highly Entangled Networks"],"prefix":"10.1002","volume":"13","author":[{"given":"Subhankar","family":"Mandal","sequence":"first","affiliation":[{"name":"ATLAS Institute University of Colorado Boulder Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saleh","family":"Assadi","sequence":"additional","affiliation":[{"name":"Paul M. Rady Department of Mechanical Engineering University of Colorado Boulder Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aseem Milind","family":"Visal","sequence":"additional","affiliation":[{"name":"Materials Science and Engineering University of Colorado Boulder Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ignacio","family":"Lorente Montero","sequence":"additional","affiliation":[{"name":"ATLAS Institute University of Colorado Boulder Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Franck J.","family":"Vernerey","sequence":"additional","affiliation":[{"name":"Paul M. Rady Department of Mechanical Engineering University of Colorado Boulder Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4285-2725","authenticated-orcid":false,"given":"Carson J.","family":"Bruns","sequence":"additional","affiliation":[{"name":"ATLAS Institute University of Colorado Boulder Colorado USA"},{"name":"Paul M. Rady Department of Mechanical Engineering University of Colorado Boulder Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,5]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaf3627"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200802106"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202303301"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abm7862"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307404"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11409"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06037-0"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b00753"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-024-00672-3"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200304907"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200305197"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201601030"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201200809"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aau3442"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202100251"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201503130"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206904"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matdes.2025.115326"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3226"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoms.2021.07.004"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3713"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201404357"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TB01511E"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202403607"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2025.102591"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b01698"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/b924290b"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301551"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202306914"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b02995"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202108243"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-023-01697-9"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316375"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature08693"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SM01487E"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.7b00729"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17877-z"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206577"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(200104)13:7<485::AID-ADMA485>3.0.CO;2-T"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b01208"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.3c00010"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c01786"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1295\/polymj.PJ2006239"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz6694"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c00970"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b01281"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202212888"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsabm.1c01052"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36920-3"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6124"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43246-022-00225-7"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202001729"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC05527E"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abg6320"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45485-8"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-4371(99)00227-7"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1RA09475K"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.0c00600"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma200123u"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevE.71.036149"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevE.74.035104"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma0203849"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.4c02021"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.4c01235"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevE.107.044501"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmps.2020.104212"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2017.03.037"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.75525","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.75525","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.75525","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T11:35:17Z","timestamp":1788867317000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.75525"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,5]]},"references-count":67,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2026,7]]}},"alternative-id":["10.1002\/advs.75525"],"URL":"https:\/\/doi.org\/10.1002\/advs.75525","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,5]]},"assertion":[{"value":"2026-02-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-16","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e75525"}}