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Herein, we propose a current\u2010dependent critical dissolution concentration (CDC) as a quantitative reference to optimize K\n                    <jats:sup>+<\/jats:sup>\n                    content, aiming to realize suppressed cyclic degradation of zinc hexacyanoferrate (ZnHCF) cathodes through precise lattice expansion control. The spontaneous dissolution of ZnHCF is theoretically analyzed via\n                    <jats:italic>Van't Hoff isothermal equation<\/jats:italic>\n                    , and a quantitative relationship between ZnHCF dissolution and K\n                    <jats:sup>+<\/jats:sup>\n                    concentration is obtained. Further, HRTEM and XRD confirm that the K\n                    <jats:sup>+<\/jats:sup>\n                    concentration below the current\u2010free CDC causes ZnHCF dissolution due to the current enrichment effect, indicating that K\n                    <jats:sup>+<\/jats:sup>\n                    concentration above CDC can trigger spontaneous ZnHCF dissolution, while K\n                    <jats:sup>+<\/jats:sup>\n                    concentration is lower than CDC, the ZnHCF layer distance is not sufficiently expanded. Based on this, the long\u2010term cycling performance of gradient K\n                    <jats:sup>+<\/jats:sup>\n                    concentration under gradient current density and in situ electrode stability tests quantifies the optimal K\n                    <jats:sup>+<\/jats:sup>\n                    ratio at each current density and successfully predicts the optimal K\n                    <jats:sup>+<\/jats:sup>\n                    concentration corresponding to a certain current density. Overall, this work advances general design guidelines for alkali metal cation additives in aqueous zinc ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/advs.75876","type":"journal-article","created":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T07:42:34Z","timestamp":1782286954000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tailoring K\n                    <sup>+<\/sup>\n                    Dosage in K\n                    <sup>+<\/sup>\n                    \/Zn\n                    <sup>2+<\/sup>\n                    Mixed Electrolytes via Lattice Expansion Regulation of Zinc Hexacyanoferrate for High\u2010performance Zinc Ion Batteries"],"prefix":"10.1002","volume":"13","author":[{"given":"Yewei","family":"Li","sequence":"first","affiliation":[{"name":"School of Energy and Power Engineering Nanjing University of Science and Technology  Nanjing China"},{"name":"School of Chemistry and Chemical Engineering Nanjing University of Science and Technology  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-4932-1334","authenticated-orcid":false,"given":"Yuqian","family":"Li","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Nanjing University of Science and Technology  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuchen","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Nanjing University of Science and Technology  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Nanjing University of Science and Technology  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanhao","family":"Pan","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Nanjing University of Science and Technology  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiyuan","family":"You","sequence":"additional","affiliation":[{"name":"Huaneng Nanjing Jinling Power Generation Co., Ltd.  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Nanjing University of Science and Technology  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenju","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Nanjing University of Science and Technology  Nanjing 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