{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T10:17:16Z","timestamp":1787912236101,"version":"build-2784847793"},"reference-count":47,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2026,6,3]],"date-time":"2026-06-03T00:00:00Z","timestamp":1780444800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,6,3]],"date-time":"2026-06-03T00:00:00Z","timestamp":1780444800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,8]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Non\u2010van\u2010der\u2010Waals (non\u2010vdW) layered magnets provide bonding degrees of freedom beyond dispersion\u2010dominated stacks, yet how dilute interlayer covalent bridges influence bulk\u2010to\u2010monolayer evolution remains insufficiently understood. Using first\u2010principles calculations, we investigate FePd\n                    <jats:sub>2<\/jats:sub>\n                    Te\n                    <jats:sub>2<\/jats:sub>\n                    (FPT), a layered ferromagnet with sparse interlayer Pd\u2500Te bridges. These bridges exhibit a covalent component, while the cleavage energy remains in the vdW\u2010like range (\u223c0.51 J\u00b7m\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), establishing FPT as an exfoliable non\u2010vdW layered magnet. Upon thinning from bulk to monolayer, local Fe moments and intralayer exchange terms increase slightly, whereas the Curie temperature decreases from 173 to 27 K. Analysis of multiplicity\u2010weighted exchange contributions indicates that this suppression of T\n                    <jats:sub>C<\/jats:sub>\n                    is governed primarily by the weakening and eventual disappearance of interlayer ferromagnetic exchange J\n                    <jats:sub>3<\/jats:sub>\n                    , with enhanced antiferromagnetic competition from J\n                    <jats:sub>2<\/jats:sub>\n                    providing an additional destabilizing contribution. Meanwhile, orbital reorganization near the Fermi level sustains a relatively large easy\u2010plane magnetocrystalline anisotropy (\u223c1.86 meV per Fe in bulk) with a moderate enhancement (\u223c8.6%) in the monolayer, gives rise to a dimensionality\u2010dependent reversal of magnetoelastic response under biaxial strain, and leaves the near\u2010E\n                    <jats:sub>F<\/jats:sub>\n                    spin polarization comparatively robust up to \u00b15% strain. These results identify FPT as a representative exfoliable non\u2010vdW magnet and clarify how sparse interlayer covalent bridges govern its thickness\u2010dependent magnetic evolution.\n                  <\/jats:p>","DOI":"10.1002\/advs.75957","type":"journal-article","created":{"date-parts":[[2026,6,3]],"date-time":"2026-06-03T15:14:03Z","timestamp":1780499643000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Sparse Pd\u2013Te Covalent Bridges Drive Anomalous Bulk\u2010to\u2010Monolayer Electronic and Magnetic Evolution in FePd\n                    <sub>2<\/sub>\n                    Te\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"13","author":[{"given":"Huaiyuan","family":"Zhao","sequence":"first","affiliation":[{"name":"Quzhou University  Quzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianwen","family":"Fang","sequence":"additional","affiliation":[{"name":"Quzhou University  Quzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohan","family":"Luo","sequence":"additional","affiliation":[{"name":"Quzhou University  Quzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yinuo","family":"Ye","sequence":"additional","affiliation":[{"name":"Quzhou University  Quzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yulin","family":"Wang","sequence":"additional","affiliation":[{"name":"Quzhou University  Quzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianhui","family":"Yang","sequence":"additional","affiliation":[{"name":"Quzhou University  Quzhou P. R. China"},{"name":"Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1358-7336","authenticated-orcid":false,"given":"Hongwen","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Lab of Materials Physics Anhui Key Lab of Nanomaterials and Nanotechnology Institute of Solid State Physics HFIPS Chinese Academy of Sciences  Hefei P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Cheng","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory of Opto\u2010electronic Functional Materials &amp; Micro\u2010Nano Devices School of Physics Renmin University of China  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,6,3]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aac9439"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010018\u20100631\u2010z"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202509453"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature22060"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature22391"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.8b09660"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-08284-6"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202411170"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2019.07.022"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.104.214410"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.105.136805"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010018\u20100040\u20106"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c01177"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04910"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04284"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c12067"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1103\/cbyr\u2010vwlw"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TC02840J"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssr.201800410"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8NR03230K"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP04835D"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.0c04794"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.100.224429"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.92.035407"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules28093893"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201015255\u20103"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c06828"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.3c05106"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC01193G"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.49.14251"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.17953"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.78.1396"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.13.5188"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.16.1748"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.16.1746"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2020.107535"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2021.108033"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811038970"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/371683a0"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/26\/10\/103202"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.82.054415"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-648X\/aaf852"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/21\/8\/084204"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20575"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3553716"}],"container-title":["Advanced 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