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Such limitations are manifested in direct\u2010doping systems, which suffer from humidity\u2010induced mechanical deterioration and sluggish excitation kinetics. Here, we overcome this fundamental limitation by molecularly locking chromophores within a poly(\n                    <jats:italic>m\u2010<\/jats:italic>\n                    xylene adipamide) (MXD6) matrix via melt doping. The engineered OPL composites leverage MXD6's exceptional barrier (oxygen transmission rate (OTR): 0.68 cm\n                    <jats:sup>3<\/jats:sup>\n                    \u00b7m\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u00b7day\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7bar\n                    <jats:sup>\u22121<\/jats:sup>\n                    ; water vapor transmission rate (WVTR): 5.3 g\u00b7m\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u00b7day\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) to achieve efficient multicolor afterglow with high quantum yields (\n                    <jats:italic>\u03a6<\/jats:italic>\n                    <jats:sub>afterglow<\/jats:sub>\n                    = 30.6%) and long lifetimes (5.6 s), operating stably without pre\u2010photoactivation. Remarkably, they retain &gt;90% of afterglow efficiency after 30 days of continuous water immersion. Integrated experimental and computational studies reveal that multiple disordered hydrogen bonding simultaneously rigidify the polymer matrix and interlock chromophores, establishing an oxygen and water barrier for triple excitons. This strategy enables meter\u2010scale homogeneous fibers and transparent films that validate industrial viability for versatile luminescent devices. This work offers a universal paradigm for ambient\u2010stable OPL polymers, solving the stability\u2010barrier trade\u2010off to unlock rapid\u2010response luminescence in demanding environmental applications.\n                  <\/jats:p>","DOI":"10.1002\/advs.76151","type":"journal-article","created":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T14:12:49Z","timestamp":1782915169000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Bypassing Pre\u2010Photoactivation in High\u2010Barrier Polyamide for Robust and Scalable Organic Persistent Luminescence"],"prefix":"10.1002","volume":"13","author":[{"given":"Yunlong","family":"Yang","sequence":"first","affiliation":[{"name":"Hunan Engineering Laboratory of Polymer Packaging Materials Hunan Provincial Key Laboratory of Advanced Packaging Materials and Technology School of Packaging Engineering Hunan University of Technology  Zhuzhou 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University  Guangzhou China"},{"name":"National Engineering Research Center for Compounding and Modification of Polymer Materials (Guizhou Material Industrial Technology Institute)  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baijun","family":"Tang","sequence":"additional","affiliation":[{"name":"Hunan Engineering Laboratory of Polymer Packaging Materials Hunan Provincial Key Laboratory of Advanced Packaging Materials and Technology School of Packaging Engineering Hunan University of Technology  Zhuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiying","family":"Guo","sequence":"additional","affiliation":[{"name":"Hunan Engineering Laboratory of Polymer Packaging Materials Hunan Provincial Key Laboratory of Advanced Packaging Materials and Technology School of Packaging Engineering Hunan University of Technology  Zhuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengtao","family":"Gao","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Compounding and Modification of Polymer Materials (Guizhou Material Industrial Technology Institute)  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xionggang","family":"Wang","sequence":"additional","affiliation":[{"name":"Hunan Engineering Laboratory of Polymer Packaging Materials Hunan Provincial Key Laboratory of Advanced Packaging Materials and Technology School of Packaging Engineering Hunan University of Technology  Zhuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9132-8017","authenticated-orcid":false,"given":"Yuejun","family":"Liu","sequence":"additional","affiliation":[{"name":"Hunan Engineering Laboratory of Polymer Packaging Materials Hunan Provincial Key Laboratory of Advanced Packaging Materials and Technology School of Packaging Engineering Hunan University of Technology  Zhuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Zheng","sequence":"additional","affiliation":[{"name":"Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi Liang","family":"Wu","sequence":"additional","affiliation":[{"name":"Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University  Hangzhou 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