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Here, we show experimentally and computationally that nanoscale curvature generates localized thermal fields that directly lower reaction barriers in heterogeneous catalysis. Using \u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    architectures with systematically varied curvature, nanoneedles, micro\u2010needles, and spheres, while maintaining comparable composition, phase, acidity, and defect states, we observe curvature\u2010dependent temperature localization of up to \u223c30 \u00b0C at nanoneedle tips under identical external heating. In situ infrared thermography confirms hotspot formation, and operando vibrational spectroscopy reveals enhanced water dissociation and increased *CF\n                    <jats:sub>3<\/jats:sub>\n                    intermediate populations during CF\n                    <jats:sub>4<\/jats:sub>\n                    decomposition. These effects reduce the apparent activation energy and enable complete CF\n                    <jats:sub>4<\/jats:sub>\n                    decomposition at 580 \u00b0C, substantially below that required for lower\u2010curvature structures. The results establish curvature\u2010induced thermal localization as a general physical mechanism linking geometry to interfacial energy density and reaction kinetics, providing a universal design principle for activating strongly bound molecules.\n                  <\/jats:p>","DOI":"10.1002\/advs.76372","type":"journal-article","created":{"date-parts":[[2026,6,28]],"date-time":"2026-06-28T12:10:21Z","timestamp":1782648621000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Curvature\u2010Controlled Field Effect Enables Thermal Localization for Low\u2010Temperature C\u2500F Bond Activation"],"prefix":"10.1002","volume":"13","author":[{"given":"Hang","family":"Zhang","sequence":"first","affiliation":[{"name":"Hunan Joint International Research Center For Carbon Dioxide Resource Utilization School of Physics Central South University  Changsha Hunan China"},{"name":"Nanoinstitute Munich Faculty of Physics 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