{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T13:55:08Z","timestamp":1790603708815,"version":"4.1.0"},"reference-count":66,"publisher":"Wiley","issue":"54","license":[{"start":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T00:00:00Z","timestamp":1784246400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T00:00:00Z","timestamp":1784246400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The electroreduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to multi\u2010carbon products provides a promising path for approaching carbon neutrality. H\n                    <jats:sub>2<\/jats:sub>\n                    O is generally considered a hydrogen source in CO\n                    <jats:sub>2<\/jats:sub>\n                    RR, tailoring the interfacial H\n                    <jats:sub>2<\/jats:sub>\n                    O configuration is critical yet often overlooked strategy for modulating CO\n                    <jats:sub>2<\/jats:sub>\n                    RR performance. In this work, we demonstrated that regulating the interfacial water configuration through ionomer confinement is an effective strategy for enhancing multi\u2010carbon (C\n                    <jats:sub>2+<\/jats:sub>\n                    ) product selectivity in CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. The optimized catalyst 15.79% A5\u2010Cu achieves 82% Faradaic efficiency (FE) for C\n                    <jats:sub>2+<\/jats:sub>\n                    products at 200\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in 0.1\u00a0M KHCO\n                    <jats:sub>3<\/jats:sub>\n                    and operates stably for over 100\u00a0h without salt precipitation in MEA system. In situ ATR\u2010SEIRAS and Raman spectroscopy revealed that the confined environment tunes the proportion between K\n                    <jats:sup>+<\/jats:sup>\n                    \u2010H\n                    <jats:sub>2<\/jats:sub>\n                    O and 4\u2010HB\u2010H\n                    <jats:sub>2<\/jats:sub>\n                    O configuration of interfacial H\n                    <jats:sub>2<\/jats:sub>\n                    O. This enhanced *H generation and transfer ability can improve the *H utilization efficiency. Moreover, a moderate *H availability constructed by the balanced proportion of K\n                    <jats:sup>+<\/jats:sup>\n                    \u2010H\n                    <jats:sub>2<\/jats:sub>\n                    O and 4\u2010HB\u2010H\n                    <jats:sub>2<\/jats:sub>\n                    O configurations lowers the energy barrier for *CO hydrogenation and subsequently C\u2500C coupling step at a higher *CO coverage, which was confirmed by DFT calculations. This work highlights the critical role of interfacial H\n                    <jats:sub>2<\/jats:sub>\n                    O configuration in steering C\n                    <jats:sub>2+<\/jats:sub>\n                    product selectivity for that in addition to *H generation, the hydrogen bonding network can accurately guide *H toward *CO intermediate, thereby avoiding excessive accumulation of *H species.\n                  <\/jats:p>","DOI":"10.1002\/advs.76470","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T19:48:50Z","timestamp":1784317730000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Promoting Electroreduction CO\n                    <sub>2<\/sub>\n                    to Multi\u2010Carbon Products by Tailoring the\n                    <sup>*<\/sup>\n                    H Availability With Optimized Interfacial H\n                    <sub>2<\/sub>\n                    O Configuration"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-2728-1236","authenticated-orcid":false,"given":"Dawei","family":"Zhou","sequence":"first","affiliation":[{"name":"Key Laboratory of Quantitative Synthetic Biology Shenzhen Institute of Synthetic Biology Shenzhen Institute of Advanced Technology Chinese Academy of Science  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Songhu","family":"Bi","sequence":"additional","affiliation":[{"name":"Key Laboratory of Quantitative Synthetic Biology Shenzhen Institute of Synthetic Biology Shenzhen Institute of Advanced Technology Chinese Academy of Science  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Quantitative Synthetic Biology Shenzhen Institute of Synthetic Biology Shenzhen Institute of Advanced Technology Chinese Academy of Science  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinghui","family":"Deng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Quantitative Synthetic Biology Shenzhen Institute of Synthetic Biology Shenzhen Institute of Advanced Technology Chinese Academy of Science  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keyi","family":"Xu","sequence":"additional","affiliation":[{"name":"Shenzhen Powered Carbon Biotechnology Co., Ltd.  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Xia","sequence":"additional","affiliation":[{"name":"Key Laboratory of Quantitative Synthetic Biology Shenzhen Institute of Synthetic Biology Shenzhen Institute of Advanced Technology Chinese Academy of Science  Shenzhen 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