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Nevertheless, simultaneously optimizing both singlet (S\n                    <jats:sub>1<\/jats:sub>\n                    ) and triplet (T\n                    <jats:sub>1<\/jats:sub>\n                    ) exciton utilization to maximize ROS generation and its subsequent effective exploitation remains challenging. Herein, a series of amphiphilic perylene\u2010based nanomicelles is designed via donor engineering, in which spatial coupling between dual\u2010path ROS generation and pollutant oxidation is achieved. Experiments and theoretical calculations certify that the micelle with triphenylamine as the donor can boost the CT efficiency of S\n                    <jats:sub>1<\/jats:sub>\n                    to engender superoxide radical (\u2022O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:bold>\n                      <jats:sup>\u2212<\/jats:sup>\n                    <\/jats:bold>\n                    ) production, while concurrently improving the intersystem crossing (ISC) efficacy from S\n                    <jats:sub>1<\/jats:sub>\n                    to T\n                    <jats:sub>1<\/jats:sub>\n                    to prolong the T\n                    <jats:sub>1<\/jats:sub>\n                    lifetime and activate the ET process for singlet oxygen (\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ) yielding. Additionally, the pre\u2010enrichment of pollutants by micelles shortens the migration distance of ROS and extends their lifetime, thereby maximizing the directed utilization efficiency of ROS. The strategy that combines photophysical properties with structural optimization, successfully surmounts the confinements of organic photocatalytic materials in solar\u2010driven chemical reactions.\n                  <\/jats:p>","DOI":"10.1002\/advs.76521","type":"journal-article","created":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T19:45:08Z","timestamp":1783799108000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["D\u2013A Type Perylene Micelles With Synergistic Charge\/Energy Transfer for Dual\u2010Path ROS Generation and Enhanced Photocatalysis"],"prefix":"10.1002","volume":"13","author":[{"given":"Chenfan","family":"Xie","sequence":"first","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science Collaborative Innovation Center of Suzhou Nano Science and Technology Soochow University  Suzhou P. R. China"},{"name":"Suzhou Laboratory  Suzhou P. R. 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