{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T11:00:07Z","timestamp":1791198007923,"version":"4.1.0"},"reference-count":88,"publisher":"Wiley","issue":"55","license":[{"start":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:00:00Z","timestamp":1783555200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:00:00Z","timestamp":1783555200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["KL3368\/3\u20101"],"award-info":[{"award-number":["KL3368\/3\u20101"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["JO257\/7"],"award-info":[{"award-number":["JO257\/7"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Nitridometallates with extended anionic frameworks exhibit a variety of intriguing electronic properties, including band magnetism, metal\u2010metal bonding, and superconductivity. Such extended framework materials are scarce with late transition metals due to the requirement of high metal oxidation states and nitrogen content. This study presents a family of nitridocobaltates\n                    <jats:italic>Ln<\/jats:italic>\n                    Co\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>Ln<\/jats:italic>\n                    = La, Pr, Nd) with an extended layered cobalt\u2010nitrogen network related to the Kagome lattice that was synthesized at 8\u00a0GPa in a large volume press. The compounds crystallize in the trigonal space group\n                    <jats:italic>R<\/jats:italic>\n                    with alternating layers of unusual trigonal planar CoN\n                    <jats:sub>3<\/jats:sub>\n                    and octahedral\n                    <jats:italic>Ln<\/jats:italic>\n                    N\n                    <jats:sub>6<\/jats:sub>\n                    polyhedra. Magnetization and powder neutron diffraction studies indicate a metallic ground state and the suppression of magnetic ordering of the rare earth moments due to their arrangement on a trigonal lattice. The compounds have a surprising mixed\u2010valent Co\n                    <jats:sup>+I\/+II<\/jats:sup>\n                    state, which is high for nitridocobaltates. This study demonstrates the structural diversity available in late nitridometallates via high\u2010pressure synthesis, which can now be explored systematically.\n                  <\/jats:p>","DOI":"10.1002\/advs.76531","type":"journal-article","created":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T14:07:39Z","timestamp":1783606059000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Extended Anionic Network in Mixed\u2010Valent Nitridocobaltates(I\/II)\n                    <i>Ln<\/i>\n                    Co\n                    <sub>2<\/sub>\n                    N\n                    <sub>2<\/sub>\n                    (\n                    <i>Ln<\/i>\n                    = La, Pr, Nd)"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-9740-3477","authenticated-orcid":false,"given":"Nina A. M.","family":"Prinz","sequence":"first","affiliation":[{"name":"Department Chemistry LMU Munich  Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-0689-5402","authenticated-orcid":false,"given":"Jonas M.","family":"Albrecht","sequence":"additional","affiliation":[{"name":"Department Chemistry LMU Munich  Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dominik","family":"Werhahn","sequence":"additional","affiliation":[{"name":"Department Chemistry LMU Munich  Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8022-7018","authenticated-orcid":false,"given":"Simon","family":"Steinberg","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clemens","family":"Ritter","sequence":"additional","affiliation":[{"name":"Institut Laue\u2010Langevin  Grenoble France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7188-5729","authenticated-orcid":false,"given":"Simon D.","family":"Klo\u00df","sequence":"additional","affiliation":[{"name":"Department Chemistry LMU Munich  Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,9]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1359\u20100286(96)80091\u2010X"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.247.4943.649"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/0925\u20108388(92)90635\u2010M"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/a807732k"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201020881\u2010y"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804369"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.202500204"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2012.04.001"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1051\/anphys\/194812030137"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812791"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4012"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201005755"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevMaterials.5.084407"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb\u20101995\u20100612"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1088\/1674\u20101056\/ae001a"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200500686"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167\u20102738(93)90098\u2010N"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u20104596(90)90242\u2010P"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.1995.1144"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u20105088(90)90171\u2010f"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0925\u20108388(98)00657\u20104"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1524\/ncrs.2007.0068"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.99.094422"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19946201020"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b02399"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010019\u20100396\u20102"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010024\u201001558\u20101"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC04001D"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108759"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202530145"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1515\/ncrs\u20102014\u20109131"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/0470010088"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567739476001551"},{"key":"e_1_2_9_35_1","volume-title":"v2024.9\u20101 ed","year":"2024"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00345a030"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1991.196.14.153"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00202a071"},{"issue":"46","key":"e_1_2_9_39_1","first-page":"1004","article-title":"The Preparation and the Crystal Structures of Cobalt Nitride, Co2N, of Cobalt Carbonitrides, Co2(C, N), and of Cobalt Carbide, Co2C","volume":"46","author":"Clarke J.","year":"1951","journal-title":"Chemistry & Industry"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200601116"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-50076-3"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg500498k"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmmm.2011.04.006"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42005\u2010022\u201000853\u2010y"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.41.194"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.93.064431"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF00899260"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.4c00425"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361\u2010648X\/ade582"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00277a030"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099\u20100682(199805)1998"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202000742"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19936190520"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201200275"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115778"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c03104"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5SC02936H"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0010\u20108545(02)00102\u20109"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00688D"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.35848\/1347\u20104065\/ae2031"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.219.6.330.34633"},{"key":"e_1_2_9_62_1","volume-title":"6.12 ed","year":"2008"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1107\/s2053273318013840"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811038970"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1088\/0957\u20100233\/19\/3\/034001"},{"key":"e_1_2_9_68_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889891010804"},{"key":"e_1_2_9_69_1","doi-asserted-by":"publisher","DOI":"10.6028\/jres.109.002"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576718000183"},{"key":"e_1_2_9_71_1","volume-title":"TOPAS Academics","year":"2007"},{"key":"e_1_2_9_72_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889869006558"},{"key":"e_1_2_9_73_1","volume-title":"Oxford Instrument","year":"2016"},{"key":"e_1_2_9_74_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470057278"},{"key":"e_1_2_9_75_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.17953"},{"key":"e_1_2_9_76_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.47.558"},{"key":"e_1_2_9_77_1","doi-asserted-by":"publisher","DOI":"10.1016\/0927\u20100256(96)00008\u20100"},{"key":"e_1_2_9_78_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169"},{"key":"e_1_2_9_79_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.59.1758"},{"key":"e_1_2_9_80_1","volume-title":"Vienna Ab\u2010initio Simulation Package VASP: The Guide, Computational Materials Physics, Faculty of Physics","author":"Kresse G.","year":"2014"},{"key":"e_1_2_9_81_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_9_82_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA05190B"},{"key":"e_1_2_9_83_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100135a014"},{"key":"e_1_2_9_84_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp202489s"},{"key":"e_1_2_9_85_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.1c00718"},{"key":"e_1_2_9_86_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c01024"},{"key":"e_1_2_9_87_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.23424"},{"key":"e_1_2_9_88_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.24300"},{"key":"e_1_2_9_89_1","volume-title":"wxDragon 2.2.3","author":"Eck B.","year":"2020"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.76531","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.76531","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.76531","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T10:06:38Z","timestamp":1791194798000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.76531"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,9]]},"references-count":88,"journal-issue":{"issue":"55","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/advs.76531"],"URL":"https:\/\/doi.org\/10.1002\/advs.76531","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,9]]},"assertion":[{"value":"2026-04-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-30","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e76531"}}