{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T18:04:37Z","timestamp":1792260277085,"version":"4.4.0"},"reference-count":61,"publisher":"Wiley","issue":"57","license":[{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004240","name":"Akademie V\u011bd \u010cesk\u00e9 Republiky","doi-asserted-by":"publisher","award":["DAAD25\u201007"],"award-info":[{"award-number":["DAAD25\u201007"]}],"id":[{"id":"10.13039\/501100004240","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Atomically precise luminescent nanoclusters (NCs) with positional isomerism originating from the coordinating ligand shell represent an important group of functional nanomaterials. We report the synthesis of two neutral isomeric [Ag\n                    <jats:sub>14<\/jats:sub>\n                    (CBDT)\n                    <jats:sub>6<\/jats:sub>\n                    (TPP)\n                    <jats:sub>4<\/jats:sub>\n                    ] NCs (where CBDT\u2010H\n                    <jats:sub>2<\/jats:sub>\n                    =\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010carborane\u20109,12\u2010dithiol, TPP = triphenylphosphine) having a stable 2e\n                    <jats:sup>\u2212<\/jats:sup>\n                    superatomic configuration with face\u2010centered cubic (fcc) Ag\n                    <jats:sub>6<\/jats:sub>\n                    @Ag\n                    <jats:sub>8<\/jats:sub>\n                    core\u2013shell geometry, where TPP ligand coordination makes the structural distinction. The positioning of four TPP ligands on the outer four Ag atoms results in distinct distortions of the Ag\n                    <jats:sub>8<\/jats:sub>\n                    cubic shell and yields two Ag\n                    <jats:sub>14<\/jats:sub>\n                    isomeric NCs: Ag\n                    <jats:sub>14<\/jats:sub>\n                    T (tetrahedral TPP binding) and Ag\n                    <jats:sub>14<\/jats:sub>\n                    S (square\u2010planar TPP binding). Density functional theory (DFT) calculations confirm a narrowed HOMO\u2010LUMO gap for Ag\n                    <jats:sub>14<\/jats:sub>\n                    S. The isomeric NCs exhibit markedly distinct photoluminescence (PL) properties, with room\u2010temperature green and red phosphorescence for Ag\n                    <jats:sub>14<\/jats:sub>\n                    T and Ag\n                    <jats:sub>14<\/jats:sub>\n                    S, respectively. The former NC shows an especially complex PL behavior with multi\u2010band emission at low temperatures. Furthermore, nanoindentation studies reveal slightly higher stiffness and hardness for Ag\n                    <jats:sub>14<\/jats:sub>\n                    S crystals than the other isomer. These findings establish phosphine binding as a versatile strategy to tune structure, luminescence, and mechanical characteristics in atomically precise NCs, enabling tailored platforms for optoelectronics and nanomechanics applications.\n                  <\/jats:p>","DOI":"10.1002\/advs.76657","type":"journal-article","created":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T12:16:02Z","timestamp":1784549762000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Isomeric Ag\n                    <sub>14<\/sub>\n                    Nanoclusters With Distinct Photophysical and Nanomechanical Properties"],"prefix":"10.1002","volume":"13","author":[{"given":"Vivek","family":"Yadav","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arijit","family":"Jana","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maya","family":"Khatun","sequence":"additional","affiliation":[{"name":"Departments of Physics and Chemistry Nanoscience Center University of Jyv\u00e4skyl\u00e4  Jyv\u00e4skyl\u00e4 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Harshita","family":"Nagar","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergei","family":"Lebedkin","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry Karlsruhe Institute of Technology (KIT)  Karlsruhe Germany"},{"name":"Institute of Nanotechnology Karlsruhe Institute of Technology (KIT)  Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amit","family":"Mondal","sequence":"additional","affiliation":[{"name":"Department of Applied Mechanics and Biomedical Engineering Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Swetashree","family":"Acharya","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sami","family":"Malola","sequence":"additional","affiliation":[{"name":"Departments of Physics and Chemistry Nanoscience Center University of Jyv\u00e4skyl\u00e4  Jyv\u00e4skyl\u00e4 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sudhadevi","family":"Antharjanam","sequence":"additional","affiliation":[{"name":"Sophisticated Analytical Instruments Facility (SAIF) Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Moses","family":"Egor","sequence":"additional","affiliation":[{"name":"Department of Syntheses Institute of Inorganic Chemistry The Czech Academy of Science  Prague Czech Republic"},{"name":"Department of Chemistry Busitema University  Tororo Uganda"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6077-6498","authenticated-orcid":false,"given":"Pijush","family":"Ghosh","sequence":"additional","affiliation":[{"name":"Department of Applied Mechanics and Biomedical Engineering Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tomas","family":"Base","sequence":"additional","affiliation":[{"name":"Department of Syntheses Institute of Inorganic Chemistry The Czech Academy of Science  Prague Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Kappes","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry Karlsruhe Institute of Technology (KIT)  Karlsruhe Germany"},{"name":"Institute of Nanotechnology Karlsruhe Institute of Technology (KIT)  Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hannu","family":"H\u00e4kkinen","sequence":"additional","affiliation":[{"name":"Departments of Physics and Chemistry Nanoscience Center University of Jyv\u00e4skyl\u00e4  Jyv\u00e4skyl\u00e4 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3174-534X","authenticated-orcid":false,"given":"Thalappil","family":"Pradeep","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,20]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00769"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00703"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00962B"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.5c01206"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI00656E"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NH00336A"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CC02594J"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5c05462"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.5c01918"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CE00651A"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/EXP.20220005"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c03979"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c06832"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201813426"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11836"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201019789\u20104"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5c01792"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC02667C"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC05666H"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424499"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201036387\u20102"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c05019"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201019327\u20102"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201056385\u2010w"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5NR03117F"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5c05462"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c03721"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NR06619J"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00896"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00962B"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2RA01080A"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5NR03845F"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202505305"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.75929"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202105692"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202508578"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201065024\u20103"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11338"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.3c01293"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c11836"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.5c00962"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adk6628"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c10289"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201055975\u2010y"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5c00033"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205002"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c02905"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/cnma.201700371"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.4c03265"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c18634"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201025275\u20102"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c03083"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c07140"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI02920H"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201070812\u20106"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202400465"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202015907"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00324"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303572"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn200053b"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1557\/JMR.1992.1564"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.76657","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.76657","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.76657","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T03:32:25Z","timestamp":1792035145000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.76657"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,20]]},"references-count":61,"journal-issue":{"issue":"57","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/advs.76657"],"URL":"https:\/\/doi.org\/10.1002\/advs.76657","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,20]]},"assertion":[{"value":"2026-05-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-07","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-20","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e76657"}}