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Here, we report a conjugated coordination polymer, Cd\u2010TMT (TMT = 1,3,5\u2010trimercaptotriazine), featuring an intrinsic molecular\u2010level charge transport network. The conjugated TMT ligands facilitate strong intra\u2010ligand charge transfer, while their ordered\n                    <jats:italic>\u03c0\u2010\u03c0<\/jats:italic>\n                    stacking along the [111] direction establishes a continuous pathway for directional electron migration, endowing Cd\u2010TMT with intrinsic photocatalytic activity for hydrogen evolution. To further promote charge separation, Cd\u2010TMT is integrated with the conductive metal\u2010organic framework Cu\u2010HHTP (HHTP = 2,3,6,7,10,11\u2010hexahydroxytriphenylene) to construct a heterostructure. Spectroscopic investigations and density functional theory calculations demonstrate that this architecture accelerates charge separation while retaining highly reductive electrons. As a result, the Cd\u2010TMT@Cu\u2010HHTP composite achieves a H\n                    <jats:sub>2<\/jats:sub>\n                    evolution rate of 9692.83 \u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , surpassing most reported MOF\u2010based photocatalysts. This work provides fundamental insights into molecular\u2010level charge transport and offers a viable strategy for designing high\u2010performance heterostructures for solar\u2010to\u2010fuel conversion.\n                  <\/jats:p>","DOI":"10.1002\/advs.76912","type":"journal-article","created":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T11:27:46Z","timestamp":1785756466000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Robust Photocatalytic Hydrogen Evolution Over a Conjugated Metal\u2010Organic Framework Heterojunction"],"prefix":"10.1002","author":[{"given":"Chunzhe","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Disaster Prevention and Ecology Protection in Open\u2010pit Coal Mines Shandong Key Laboratory of Special Epoxy Resin School of Materials Science and Engineering Shandong University of Science and Technology  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufei","family":"Shan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Disaster Prevention and Ecology Protection in Open\u2010pit Coal Mines Shandong Key Laboratory of Special Epoxy Resin School of Materials Science and Engineering Shandong University of Science and Technology  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruobing","family":"Chu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Disaster Prevention and Ecology Protection in Open\u2010pit Coal Mines Shandong Key Laboratory of Special Epoxy Resin School of Materials Science and Engineering Shandong University of Science and Technology  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingzhi","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Disaster Prevention and Ecology Protection in Open\u2010pit Coal Mines Shandong Key Laboratory of Special Epoxy Resin School of Materials Science and Engineering Shandong University of Science and Technology  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3399-0448","authenticated-orcid":false,"given":"Zhanning","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Disaster Prevention and Ecology Protection in Open\u2010pit Coal Mines Shandong Key Laboratory of Special Epoxy Resin School of Materials Science and Engineering Shandong University of Science and Technology  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4226-7622","authenticated-orcid":false,"given":"Xiaoli","family":"Zhang","sequence":"additional","affiliation":[{"name":"Australian Research Council Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide Applied Chemistry and Environmental Science School of Science RMIT University  Melbourne VIC Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9334-9409","authenticated-orcid":false,"given":"Jian","family":"Tian","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Disaster Prevention and Ecology Protection in Open\u2010pit Coal Mines Shandong Key Laboratory of Special Epoxy Resin School of Materials Science and Engineering Shandong University of Science and Technology  Qingdao 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