{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T16:31:12Z","timestamp":1786638672030,"version":"build-2736575974"},"reference-count":44,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T00:00:00Z","timestamp":1786579200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T00:00:00Z","timestamp":1786579200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100009553","name":"Bundesanstalt f\u00fcr Materialforschung und -Pr\u00fcfung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100009553","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["517014885"],"award-info":[{"award-number":["517014885"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100013110","name":"Helmholtz-Zentrum Berlin f\u00fcr Materialien und Energie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100013110","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    This study investigates sulfur spillover, the spontaneous and rapid spread of sulfur over carbon surfaces at ambient temperature. The process is studied by small\u2010angle X\u2010ray scattering (SAXS), X\u2010ray radiography, and microcalorimetry from which a number of physicochemical properties are derived. The results confirm that sulfur immediately interacts with porous carbon upon mixing, with most signal changes occurring within a few hours. For the first time, thermodynamic data of the process are determined. Using microcalorimetry, the lower bound of the reaction enthalpy is determined to be \u0394\n                    <jats:sub>sp<\/jats:sub>\n                    <jats:italic>H<\/jats:italic>\n                    = \u221228.2\u00a0kJ\u00a0mol\n                    <jats:sub>S8<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    . With an estimated reaction entropy of \u0394\n                    <jats:sub>sp<\/jats:sub>\n                    <jats:italic>S<\/jats:italic>\n                    = 273.78\u00a0J\u00a0mol\n                    <jats:sub>S8<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0K\n                    <jats:sup>\u22121<\/jats:sup>\n                    , the Gibbs Free Energy of the spillover process is estimated as \u0394\n                    <jats:sub>sp<\/jats:sub>\n                    <jats:italic>G<\/jats:italic>\n                    = \u2212100.23\u00a0kJ\u00a0mol\n                    <jats:sub>S8<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which reduces the theoretical cell voltage of Li\u2010S batteries by about 64\u00a0mV. Furthermore, depending on the configuration, DFT calculations have revealed repulsive and attractive interactions; the latter are caused by defects that eventually result in ring opening and the formation of S\u2500C bonds. This suggests that spillover includes various processes that occur simultaneously. Considering metal\u2010sulfur batteries, sulfur spillover may be critical for preparing and cycling sulfur\u2010carbon composite cathodes, which is demonstrated for a Li\u2013S solid\u2010state battery.\n                  <\/jats:p>","DOI":"10.1002\/advs.76931","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T15:37:26Z","timestamp":1786635446000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Further Evidences for the Sulfur Spillover on Carbon: Thermodynamic Aspects and Effects on Li\u2010S Solid\u2010State Batteries"],"prefix":"10.1002","author":[{"given":"Francesco","family":"Piccolo","sequence":"first","affiliation":[{"name":"Institute of Chemistry Humboldt\u2010Universit\u00e4t zu Berlin  Berlin Germany"},{"name":"Research Group Operando Battery Analysis (CE\u2010GOBA) Helmholtz\u2010Zentrum Berlin f\u00fcr Materialien und Energie (HZB)  Berlin 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University of Technology  Chemnitz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00f6rg","family":"Schuster","sequence":"additional","affiliation":[{"name":"Chemnitz University of Technology  Chemnitz Germany"},{"name":"Fraunhofer Institute for Electronic Nano Systems  Chemnitz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2914-0600","authenticated-orcid":false,"given":"Marc","family":"Armbr\u00fcster","sequence":"additional","affiliation":[{"name":"Inorganic Solid State and Material Chemistry Eduard\u2010Zintl\u2010Institute Technical University Darmstadt  Darmstadt Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2439-8802","authenticated-orcid":false,"given":"Philipp","family":"Adelhelm","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Humboldt\u2010Universit\u00e4t zu Berlin  Berlin Germany"},{"name":"Research Group 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