{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T20:33:18Z","timestamp":1791232398563,"version":"4.1.0"},"reference-count":43,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T00:00:00Z","timestamp":1785456000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T00:00:00Z","timestamp":1785456000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100000921","name":"European Cooperation in Science and Technology","doi-asserted-by":"publisher","award":["CA21148"],"award-info":[{"award-number":["CA21148"]}],"id":[{"id":"10.13039\/501100000921","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Dopant\u2010free inorganic hole\u2010transport layers (HTLs) are promising for improving the efficiency and stability of perovskite solar cells (PSCs). Here, CuSbS\n                    <jats:sub>2<\/jats:sub>\n                    nanocrystals are engineered through sulfur\u2010precursor and ligand\u2010coordination chemistry using hexamethyldisilathiane (TMS) and thiourea (ThU) combined with oleylamine\/oleic acid (OAm\/OAc) ligands. While the TMS route reduces platelet dimensions, the ThU precursor with an optimized OAm: OAc ratio of 3:7 suppresses excessive anisotropic growth and induces mixed plate\u2010like\/quasi\u2010spherical nanostructures, leading to denser particle packing and improved interfacial coverage. Structural and electronic analyses reveal that sulfur\u2010release kinetics and ligand coordination govern morphology evolution, energetic disorder, and interfacial charge\u2010transfer behavior. As a result, PSCs employing ThU\u2010derived CuSbS\n                    <jats:sub>2<\/jats:sub>\n                    HTLs achieve a champion power conversion efficiency of 22.72% with 0.82 for fill factor, outperforming TMS\u2010derived (20.00%) and ES\u2010derived (17.31%) counterparts. The optimized devices also exhibit enhanced operational stability under illumination and thermal aging conditions. These findings establish sulfur\u2010precursor and ligand engineering as an effective strategy for high\u2010performance inorganic HTLs in PSCs.\n                  <\/jats:p>","DOI":"10.1002\/advs.76977","type":"journal-article","created":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T18:56:26Z","timestamp":1785524186000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Suppressing Morphological and Energetic Disorder in Copper Antimony Sulfide\u2010based Hole\u2010Transporting Materials via Ligand\u2013Precursor Engineering for Efficient and Stable Perovskite Solar Cells"],"prefix":"10.1002","author":[{"given":"Ibrahimhan","family":"Dilci","sequence":"first","affiliation":[{"name":"Department of Metallurgical and Materials Engineering Karamanoglu Mehmetbey University  Karaman T\u00fcrkiye"},{"name":"Nanotechnology R&amp;D Laboratory Karamanoglu Mehmetbey University  Karaman T\u00fcrkiye"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6011-3504","authenticated-orcid":false,"given":"Savas","family":"Sonmezoglu","sequence":"additional","affiliation":[{"name":"Department of Metallurgical and Materials Engineering Karamanoglu Mehmetbey University  Karaman T\u00fcrkiye"},{"name":"Nanotechnology R&amp;D Laboratory Karamanoglu Mehmetbey University  Karaman T\u00fcrkiye"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,31]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja809598r"},{"key":"e_1_2_8_3_1","unstructured":"Best Research\u2010Cell Efficiency Chart (US Department of Energy 1976) https:\/\/www.nlr.gov\/pv\/cell\u2010efficiency."},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201902851"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.132701"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010025\u201000781\u20107"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43246\u2010022\u201000281\u2010z"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202522825"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.201800882"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/ente.202201005"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00262B"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010023\u201000582\u2010w"},{"key":"e_1_2_8_13_1","doi-asserted-by":"crossref","first-page":"181","DOI":"10.1016\/B978-0-12-820628-7.00008-3","volume-title":"Sustainable Materials for Next Generation Energy Devices","author":"Kaya I. 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