{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T10:11:35Z","timestamp":1788775895986,"version":"build-2803163510"},"reference-count":55,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The development of porous materials that combine low\u2010temperature meltability with high gas uptake remains a major challenge. Herein, we report Cu\u2010BCN\u20105, a polymer\u2010grafted Cu(II) metal\u2013organic polyhedron (MOP), as a scalable melt\u2010processable material with intrinsic porosity. This material melts at 44\u00b0C while preserving cage integrity and accessible porosity. By overcoming diffusion limitations imposed by the polymer corona during sorption measurements, the material reaches a CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake of 0.68\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 298 K and 1\u00a0bar, the highest value reported for melt\u2010processable porous materials under these conditions. Furthermore, the molten state enables fabrication of dense, grain\u2010boundary\u2010free macroscopic objects that retain high adsorption performance after shaping. These results establish Cu(II)\u2010based MOPs as a scalable platform for melt\u2010processable porous materials.\n                  <\/jats:p>","DOI":"10.1002\/advs.77006","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T09:46:45Z","timestamp":1788774405000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Polymer\u2010Grafted Cu(II) Metal\u2013Organic Polyhedra as Scalable, Melt\u2010Processable Porous Materials"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1679-5955","authenticated-orcid":false,"given":"Alba","family":"Cort\u00e9s\u2010Mart\u00ednez","sequence":"first","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology  Bellaterra Barcelona Spain"},{"name":"Departament de Qu\u00edmica Facultat de Ci\u00e8ncies Universitat Aut\u00f2noma de Barcelona (UAB)  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