{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T13:24:04Z","timestamp":1786973044679,"version":"build-2736575974"},"reference-count":34,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100007000","name":"Laboratory Directed Research and Development","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007000","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006224","name":"Argonne National Laboratory","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006224","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrochemical carbon dioxide reduction reaction (eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR) provides a pathway to convert CO\n                    <jats:sub>2<\/jats:sub>\n                    into value\u2010added chemicals. Here, we report a family of carbon\u2010supported tin\u2013copper (Sn\u2013Cu) bimetallic catalysts synthesized via an amalgamated lithium metal (ALM) method with controlled tuning of metal dispersion from isolated atoms to nanocrystallites. As metal loadings increase, the catalyst structure evolves from atomically dispersed Sn\u2010Cu dual sites (Sn\n                    <jats:sub>1.5<\/jats:sub>\n                    Cu\/C\u20100.75) to Sn\u2010rich nanodomains (Sn\n                    <jats:sub>3<\/jats:sub>\n                    Cu\/C\u201013) and Cu\/Sn crystallites (Sn\n                    <jats:sub>3<\/jats:sub>\n                    Cu\/C\u201024), leading to a systematic shift in CO\n                    <jats:sub>2<\/jats:sub>\n                    RR selectivity from acetaldehyde to formate at low overpotentials. Notably, Sn\n                    <jats:sub>1.5<\/jats:sub>\n                    Cu\/C\u20100.75 achieves a Faradaic efficiency of 49.7% for acetaldehyde at \u22120.5 V versus the reversible hydrogen electrode. The CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion pathways behind these selective, size\u2010modulated catalysts are elucidated by structural characterization, together with electrochemical analysis of structure\u2010selectivity correlations, establishing a clear structure\u2010property relationship for tuning CO\n                    <jats:sub>2<\/jats:sub>\n                    RR pathways.\n                  <\/jats:p>","DOI":"10.1002\/advs.77199","type":"journal-article","created":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T12:24:01Z","timestamp":1786969441000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction over Sn\u2010Cu Bimetallic Catalysts Synthesized via an Amalgamated Lithium Metal Method"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3781-5118","authenticated-orcid":false,"given":"Minghao","family":"Xie","sequence":"first","affiliation":[{"name":"Chemical Sciences and Engineering Division Argonne National Laboratory  Lemont Illinois United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8864-9055","authenticated-orcid":false,"given":"Shichen","family":"Guo","sequence":"additional","affiliation":[{"name":"Chemical Sciences and Engineering Division Argonne National Laboratory  Lemont Illinois United States"},{"name":"Energy Systems and Infrastructure Assessment Division Argonne National Laboratory  Lemont Illinois United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianxin","family":"Wang","sequence":"additional","affiliation":[{"name":"Chemical Sciences and Engineering Division Argonne National Laboratory  Lemont Illinois United 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States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1747-028X","authenticated-orcid":false,"given":"Di\u2010Jia","family":"Liu","sequence":"additional","affiliation":[{"name":"Chemical Sciences and Engineering Division Argonne National Laboratory  Lemont Illinois United States"},{"name":"Pritzker School of Molecular Engineering The University of Chicago  Chicago Illinois United 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