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Herein, we report the first Ni\/photoredox\u2010catalyzed stereoconvergent C(sp\n                    <jats:sup>3<\/jats:sup>\n                    )\u2212C(sp\n                    <jats:sup>2<\/jats:sup>\n                    ) cross\u2010electrophile coupling of racemic epoxides with alkenyl bromides, delivering\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010alkenyl phenylethanol with high enantioselectivity (up to 95% ee), excellent\n                    <jats:italic>E<\/jats:italic>\n                    \u2010stereoselectivity, and complete regiocontrol. The enantioenriched products serve as versatile intermediates for diverse chiral synthons, enabling further applications. Mechanistic studies suggest a stereoconvergent pathway involving regioselective halide ring\u2010opening of epoxides, followed by enantioselective coupling of the generated\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010hydroxy benzyl halides with alkenyl bromides.\n                  <\/jats:p>","DOI":"10.1002\/advs.77326","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T07:16:15Z","timestamp":1787987775000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dual Nickel\/Photoredox\u2010Catalyzed Regio\u2010 and Enantioselective Alkenylation of Epoxides"],"prefix":"10.1002","volume":"13","author":[{"given":"Hongyan","family":"Lan","sequence":"first","affiliation":[{"name":"College of Sciences Northeastern University  Shenyang 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