{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T16:34:29Z","timestamp":1787330069671,"version":"build-2736575974"},"reference-count":57,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100008206","name":"Australian Nuclear Science and Technology Organisation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100008206","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction offers a sustainable route to convert greenhouse gas into high\u2010value\u2010added chemicals, yet product distributions remain largely limited to simple C\n                    <jats:sub>1<\/jats:sub>\n                    \u2010C\n                    <jats:sub>3<\/jats:sub>\n                    molecules. Here, we report a new reaction in which CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction intermediates undergo direct C\u2010C coupling with an external carbon nucleophile under electrochemical conditions. Using cobalt phthalocyanine supported on multi\u2010walled carbon nanotubes (CoPc\/MWCNT) as a catalyst, cyanide ions intercept deeply reduced C\n                    <jats:sub>1<\/jats:sub>\n                    intermediates to produce glycolonitrile at 4\u00b0C with a faradaic efficiency (FE) of up to 6.6%. Combined electrochemical analysis, control experiments, and density functional theory calculations identify *CH\n                    <jats:sub>2<\/jats:sub>\n                    O as the key coupling intermediate, revealing a C\u2010C coupling mechanism fundamentally different from conventional coupling pathways in CO\n                    <jats:sub>2<\/jats:sub>\n                    electroreduction to synthesize C\n                    <jats:sub>2+<\/jats:sub>\n                    compounds. Extending this concept to a three\u2010component reaction involving hydroxylamine (NH\n                    <jats:sub>2<\/jats:sub>\n                    OH) enables electrocatalytic synthesis of glycine under ambient pressure with a FE of 2.8%. This work establishes a new strategy for constructing complex carbon skeletons directly from CO\n                    <jats:sub>2<\/jats:sub>\n                    and external nucleophiles, expanding the synthetic scope of electrochemical carbon conversion.\n                  <\/jats:p>","DOI":"10.1002\/advs.77346","type":"journal-article","created":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T15:46:41Z","timestamp":1787327201000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrocatalytic C\u2500C Bond Formation Via Cyanide Interception of CO\n                    <sub>2<\/sub>\n                    Reduction Intermediates"],"prefix":"10.1002","author":[{"given":"Gongbo","family":"Liu","sequence":"first","affiliation":[{"name":"School of Chemistry Monash University  Clayton Melbourne Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liuru","family":"Fang","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Melbourne Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-5426-0772","authenticated-orcid":false,"given":"Dayu","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Melbourne Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aimin","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Melbourne Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoming","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Melbourne 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2629-3895","authenticated-orcid":false,"given":"San H.","family":"Thang","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Melbourne Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2493-5209","authenticated-orcid":false,"given":"Jie","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Melbourne Australia"},{"name":"ARC Research Hub For Carbon Utilisation and Recycling Monash University  Clayton Australia"},{"name":"ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide Monash University  Clayton 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