{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T06:06:54Z","timestamp":1788934014516,"version":"build-2803163510"},"reference-count":84,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T00:00:00Z","timestamp":1788825600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T00:00:00Z","timestamp":1788825600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The growing demand for energy storage systems (ESS) driven by the expansion of renewable energy calls for aqueous Zn\u2013I\n                    <jats:sub>2<\/jats:sub>\n                    batteries that offer both safety and cost competitiveness. However, the hydrogen evolution reaction (HER) and Zn anode corrosion, combined with iodine dissolution and polyiodide shuttling at the I\n                    <jats:sub>2<\/jats:sub>\n                    cathode, form a degradation loop through interelectrode interactions, that impairs battery lifespan and efficiency. This study proposes a dual\u2010interface regulation strategy by introducing the multidentate chelator TPEN as an electrolyte additive. This strategy promotes the formation of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    \u2013TPEN coordination species (TCC) in the electrolyte, which reconfigures the electric double layer of Zn anode into an interfacial environment with reduced water accessibility via interfacial adsorption, suppressing HER and corrosion, and stabilizing local pH fluctuations while promoting uniform nucleation and deposition. Simultaneously, at the I\n                    <jats:sub>2<\/jats:sub>\n                    cathode, it traps polyiodide to reduce free polyiodide concentration and directs the reaction pathway toward the interface, thereby decreasing shuttling and self\u2010discharge while improving I\n                    <jats:sub>2<\/jats:sub>\n                    deposition uniformity. As a result, the Zn||Zn symmetric cell operated stably for over 2000\u00a0h and achieved a Coulombic efficiency of over 96.2% and a capacity retention of 92.5% after 200 cycles under high\u2010loading I\n                    <jats:sub>2<\/jats:sub>\n                    (5.5\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) and 0.18 C conditions.\n                  <\/jats:p>","DOI":"10.1002\/advs.77565","type":"journal-article","created":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T05:34:45Z","timestamp":1788932085000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Chelation\u2010Driven Dual\u2010Interface Regulation for Long\u2010Life Aqueous Zn\u2013I\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4169-0509","authenticated-orcid":false,"given":"Dong Wook","family":"Kim","sequence":"first","affiliation":[{"name":"Advanced Batteries Research Center Korea Electronics Technology Institute  Seongnam Gyeonggi\u2010do Republic of Korea"},{"name":"School of Chemical Engineering Sungkyunkwan University  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seung Hwa","family":"Park","sequence":"additional","affiliation":[{"name":"Advanced Batteries Research Center Korea Electronics Technology Institute  Seongnam Gyeonggi\u2010do Republic of Korea"},{"name":"School of Chemical Engineering Sungkyunkwan University  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tae Rim","family":"Kim","sequence":"additional","affiliation":[{"name":"Advanced Batteries Research Center Korea Electronics Technology Institute  Seongnam Gyeonggi\u2010do Republic of Korea"},{"name":"School of Chemical Engineering Sungkyunkwan University  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gun","family":"Jang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sungkyunkwan University  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7711-3992","authenticated-orcid":false,"given":"Jun Su","family":"Kim","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sungkyunkwan University  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Myung\u2010Jun","family":"Kwak","sequence":"additional","affiliation":[{"name":"Advanced Batteries Research Center Korea Electronics Technology Institute  Seongnam Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seokhwan","family":"Jin","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering College of Engineering Kyung Hee University  Yongin Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2730-9249","authenticated-orcid":false,"given":"Seongbin","family":"Ga","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering University of Ulsan  Ulsan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7469-3119","authenticated-orcid":false,"given":"Chihyun","family":"Hwang","sequence":"additional","affiliation":[{"name":"Advanced Batteries Research Center Korea Electronics Technology Institute  Seongnam Gyeonggi\u2010do Republic of Korea"},{"name":"School of Chemical Biological &amp; Battery Engineering Gachon University  Seongnam\u2010si Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4424-4037","authenticated-orcid":false,"given":"Ho Seok","family":"Park","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sungkyunkwan University  Suwon Gyeonggi\u2010do Republic of Korea"},{"name":"SKKU Institute of Energy Science and Technology (SIEST) Sungkyunkwan University (SKKU)  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6870-8118","authenticated-orcid":false,"given":"Youngkwon","family":"Kim","sequence":"additional","affiliation":[{"name":"Advanced Batteries Research Center Korea Electronics Technology Institute  Seongnam Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,8]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"crossref","DOI":"10.1002\/aenm.202501201","article-title":"Achieving High Energy Density in Aqueous Zinc\u2010Ion Batteries","volume":"15","author":"Kao C. 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