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Here, we propose a ternary water\u2010deficient eutectic electrolyte without water solvent whose polarization approaches that of aqueous systems by engineering a weakly coordinated solvent network via solvation\u2010structure restructuring. A strongly coordinated solvent network enables salt dissolution, whereas the introduction of a weakly coordinating co\u2010solvent disrupts the constrained coordination environment and drives a transition to a dynamic, weakly coordinated solvation structure. This restructuring enhances anion participation while suppressing ion bridging, yielding abundant yet size\u2010confined aggregates, thereby accelerating ion\u2010transport kinetics and lowering desolvation barriers. Furthermore, the formation of a robust solid\u2010electrolyte interphase effectively stabilizes the Zn anode. As a result, the ternary water\u2010deficient electrolyte enables highly reversible Zn plating\/stripping with low polarization under ambient conditions, while also delivering excellent low\u2010temperature performance. Enhanced kinetics in Zn||PANI cells and consistent performance across both coin cells and printed energy devices highlight the strong potential of this water\u2010deficient eutectic electrolyte for scalable zinc\u2010ion energy storage.<\/jats:p>","DOI":"10.1002\/advs.77566","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T04:20:35Z","timestamp":1788754835000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Weakly Coordinated Solvent Network\u2010Induced Ternary Water\u2010Deficient Eutectic Electrolytes for Low\u2010Polarization Zn Anodes"],"prefix":"10.1002","author":[{"given":"Quancai","family":"Li","sequence":"first","affiliation":[{"name":"Laboratory of Printable Functional Materials and Printed Electronics School of Physics and Technology Renmin Hospital of Wuhan University Wuhan University  Wuhan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Liang","sequence":"additional","affiliation":[{"name":"Laboratory of Printable Functional Materials and Printed Electronics School of Physics and Technology Renmin Hospital of Wuhan University Wuhan University  Wuhan People's Republic of China"},{"name":"School of Science and Technology Hong Kong Metropolitan University  Ho Man Tin Hong Kong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayu","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Clinical Laboratory Institute of Translational Medicine Renmin Hospital of Wuhan University  Wuhan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Wang","sequence":"additional","affiliation":[{"name":"Laboratory of Printable Functional Materials and Printed Electronics School of Physics and Technology Renmin Hospital of Wuhan University Wuhan University  Wuhan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hehe","family":"Ren","sequence":"additional","affiliation":[{"name":"Laboratory of Printable Functional Materials and Printed Electronics School of Physics and Technology Renmin Hospital of Wuhan University Wuhan University  Wuhan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyi","family":"Gong","sequence":"additional","affiliation":[{"name":"Laboratory of Printable Functional Materials and Printed Electronics School of Physics and Technology Renmin Hospital of Wuhan University Wuhan University  Wuhan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1432-9950","authenticated-orcid":false,"given":"Vellaisamy A. 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