{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T06:03:38Z","timestamp":1789365818401,"version":"build-2803163510"},"reference-count":82,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,13]],"date-time":"2026-09-13T00:00:00Z","timestamp":1789257600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,13]],"date-time":"2026-09-13T00:00:00Z","timestamp":1789257600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52125105"],"award-info":[{"award-number":["52125105"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22475231"],"award-info":[{"award-number":["22475231"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52561040"],"award-info":[{"award-number":["52561040"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52474431"],"award-info":[{"award-number":["52474431"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Lithium\u2010oxygen batteries (LOBs) deliver ultrahigh theoretical specific energy but suffer from limited cycle life caused by lithium dendrite growth, anode corrosion, and cathode passivation. Developing interfacially compatible functional separators is an effective solution, yet coordinating fast ion conduction and multi\u2010species mass transport regulation remains challenging. We design an asymmetric multifunctional mesoporous Janus separator (mGP), consisting of a \u223c 3.16 nm mesoporous silica (mSiO\n                    <jats:sub>2<\/jats:sub>\n                    ) layer and dense, hydrophobic, mechanically tough polyurethane (PU). Via steric confinement, the mSiO\n                    <jats:sub>2<\/jats:sub>\n                    nanochannels optimize mass transport behavior: they homogenize Li\n                    <jats:sup>+<\/jats:sup>\n                    flux and accelerate ion transport, suppress intermediate crossover to alleviate the shuttle effect and cathode passivation. The PU layer prevents dendrite piercing, buffers lithium volume variation, and suppresses water\u2010 and intermediate\u2010triggered anode corrosion via hydrophobicity. Li||Li symmetric cells with mGP run stably for 1300 h at 0.1 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . LOBs based on mGP achieve exceptional cycling stability: over 800 cycles at 1000 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and 100 cycles at 3000 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , outperforming traditional glass fiber (GF) separators. This work provides a feasible strategy for constructing high\u2010performance long\u2010cycle LOBs through deliberate mass transport optimization.\n                  <\/jats:p>","DOI":"10.1002\/advs.77588","type":"journal-article","created":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T05:27:08Z","timestamp":1789363628000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Multifunctional Mesoporous Janus Separator With Optimized Mass Transport Regulation Enabling 800\u2010Cycle Lithium\u2010Oxygen Batteries"],"prefix":"10.1002","author":[{"given":"Hailiang","family":"Mu","sequence":"first","affiliation":[{"name":"Jiangsu Province Engineering Research Centre of Intelligent Manufacturing Technology for the New Energy Vehicle Power Battery School of Materials Science &amp;Engineering Changzhou University  Changzhou People's Republic of China"},{"name":"Advanced Energy Storage Technology Research Center Shenzhen Institutes of Advanced Technology Chinese Academy of Sciences  Shenzhen People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-6389-7689","authenticated-orcid":false,"given":"Anlong","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Mechanical Engineering Shanghai Jiao Tong University  Shanghai People's Republic of China"},{"name":"Geely Automobile Research Institute (Ningbo) Co., Ltd.  Ningbo People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6526-4304","authenticated-orcid":false,"given":"Kun","family":"Luo","sequence":"additional","affiliation":[{"name":"Jiangsu Province Engineering Research Centre of Intelligent Manufacturing Technology for the New Energy Vehicle Power Battery School of Materials Science &amp;Engineering Changzhou University  Changzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaming","family":"Pang","sequence":"additional","affiliation":[{"name":"Jiangsu Province Engineering Research Centre of Intelligent Manufacturing Technology for the New Energy Vehicle Power Battery School of Materials Science &amp;Engineering Changzhou University  Changzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengde","family":"Xie","sequence":"additional","affiliation":[{"name":"Advanced Energy Storage Technology Research Center Shenzhen Institutes of Advanced Technology Chinese Academy of Sciences  Shenzhen People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7574-1709","authenticated-orcid":false,"given":"Xiaoteng","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Engineering, Physics and Mathematics, Faculty of Science and Environment Northumbria University  Newcastle upon Tyne UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4344-1004","authenticated-orcid":false,"given":"Zhihong","family":"Luo","sequence":"additional","affiliation":[{"name":"Guangxi Key Laboratory of Optical and Electronic Materials and Devices Guilin University of Technology  Guilin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangbin","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Tianjin University  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yucheng","family":"Wang","sequence":"additional","affiliation":[{"name":"Jiangsu Province Engineering Research Centre of Intelligent Manufacturing Technology for the New Energy Vehicle Power Battery School of Materials Science &amp;Engineering Changzhou University  Changzhou People's Republic of China"},{"name":"School of Engineering, Physics and Mathematics, Faculty of Science and Environment Northumbria University  Newcastle upon Tyne UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4776-2825","authenticated-orcid":false,"given":"Qirong","family":"Liu","sequence":"additional","affiliation":[{"name":"Advanced Energy Storage Technology Research Center Shenzhen Institutes of Advanced Technology Chinese Academy of Sciences  Shenzhen People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2705-4618","authenticated-orcid":false,"given":"Yongbing","family":"Tang","sequence":"additional","affiliation":[{"name":"Advanced Energy Storage Technology Research Center Shenzhen Institutes of Advanced Technology Chinese Academy of Sciences  Shenzhen People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,13]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202404319","article-title":"Constructing an Interlaced Catalytic Surface via Fluorine\u2010Doped Bimetallic Oxides for Oxygen Electrode Processes in Li\u2010O2 Batteries","volume":"36","author":"Sun Z.","year":"2024","journal-title":"Advanced Materials"},{"key":"e_1_2_8_3_1","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202405715","article-title":"A High Capacity Gas Diffusion Electrode for Li\u2010O2 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