{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T14:07:43Z","timestamp":1789135663909,"version":"build-2803163510"},"reference-count":50,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T00:00:00Z","timestamp":1789084800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T00:00:00Z","timestamp":1789084800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100007053","name":"Korea Institute of Energy Technology Evaluation and Planning","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100007053","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS\u20102026\u201025493661"],"award-info":[{"award-number":["RS\u20102026\u201025493661"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The surface modification of zinc anodes and the development of effective cathode dual\u2010functional oxygen electrocatalysts remain of paramount interest for enhancing the cycle life of rechargeable zinc\u2010air batteries. The present work provides a sustainable synthesis of CoNi\u2010based composites that can be used as cathode and anode side catalysts in Zn\u2010air batteries. CoNi\u2010metals with hybrid\u2010metal organic frameworks (Hybrid\u2010MOFs) and MOF\u2010derived composites from curcumin\u2010melamine (C\u2010M) and benzene\u20101,3,5\u2010tricarboxylic acid (BTC) were created for cathode and anode composites using reflux and hydrothermal techniques. In this instance, the cathode composite can be referred to as CoNi\u2010N\u2010C after annealing, whereas the anode composite can be referred to as CoNi\u2010BTC without annealing. Thereafter, the formation of CoNi\u2010N\u2010C and CoNi\u2010BTC composites was confirmed by microscopic, X\u2010ray photoelectron, and X\u2010ray diffraction techniques. As a result, structurally tailored CoNi\u2010N\u2010C and CoNi\u2010BTC composites perform efficiently in electrochemical processes such as oxygen evolution\/reduction reactions (OER\/ORR) and energy conversion devices (Zn\u2010air battery). Primarily, the CoNi\u2010N\u2010C catalyst exhibits the lowest overpotential (E\n                    <jats:sub>i\u00a0=\u00a010<\/jats:sub>\n                    \u00a0=\u00a01.48\u00a0V) and better half\u2010wave potential (E\n                    <jats:sub>1\/2<\/jats:sub>\n                    \u00a0=\u00a00.781\u00a0V) in OER\/ORR reactions; secondary CoNi\u2010BTC composites coated on the Zn anode have the highest specific capacity (756.3\u00a0mA\u00a0h\u00a0g\n                    <jats:sub>zn<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and 1000\u2010cycle charge\u2013discharge stability in Zn\u2010air batteries.\n                  <\/jats:p>","DOI":"10.1002\/advs.77650","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T13:21:11Z","timestamp":1789132871000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Hybrid Metal\u2013Organic Framework\u2010Derived Dual Active Site Catalysts Enabling Surface\u2010Enriched Cathode and Modified Zinc Anode for Long\u2010Life Zinc\u2013Air Batteries"],"prefix":"10.1002","author":[{"given":"Ramasamy Santhosh","family":"Kumar","sequence":"first","affiliation":[{"name":"Department of Energy Storage\/Conversion Engineering of Graduate School BK21 FOUR, Hydrogen and Fuel Cell Research Center Jeonbuk National University Jeollabuk\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Duraisami","family":"Kaviyarasu","sequence":"additional","affiliation":[{"name":"Department of Energy Storage\/Conversion Engineering of Graduate School BK21 FOUR, Hydrogen and Fuel Cell Research Center Jeonbuk National University Jeollabuk\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dilmurod","family":"Sayfiddinov","sequence":"additional","affiliation":[{"name":"Department of Energy Storage\/Conversion Engineering of Graduate School BK21 FOUR, Hydrogen and Fuel Cell Research Center Jeonbuk National University Jeollabuk\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1208-5879","authenticated-orcid":false,"given":"Murugavel","family":"Kathiresan","sequence":"additional","affiliation":[{"name":"P. C. Ray Department of Chemistry National Institute of Technology Puducherry  Karaikal Puducherry India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4373-0938","authenticated-orcid":false,"given":"Pandian","family":"Mannu","sequence":"additional","affiliation":[{"name":"Research Center for X\u2010ray Science Department of Physics Tamkang University  Tamsui Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4289-4677","authenticated-orcid":false,"given":"Chung\u2010Li","family":"Dong","sequence":"additional","affiliation":[{"name":"Research Center for X\u2010ray Science Department of Physics Tamkang University  Tamsui Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8533-5165","authenticated-orcid":false,"given":"Arul Manuel","family":"Stephan","sequence":"additional","affiliation":[{"name":"CSIR\u2010Central Electrochemical Research 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