{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T05:07:26Z","timestamp":1789103246398,"version":"build-2803163510"},"reference-count":47,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T00:00:00Z","timestamp":1788998400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T00:00:00Z","timestamp":1788998400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Scaling up aqueous zinc (Zn)\u2010ion batteries with long cycling stability and calendar life (i.e., long rest periods at open\u2010circuit potential) remains challenging, particularly with the use of a thick Zn foil anode. A more practical and scalable approach involves adopting a lean\u2010Zn configuration with a current collector. Due to the limited Zn availability, lean Zn anodes experience different failure mechanisms, manifested as Zn pulverization in cycle life and galvanic corrosion during calendar life. Unfortunately, these issues have long been overlooked. Herein, we introduce benzotriazole (BTA), a well\u2010known corrosion inhibitor, as an electrolyte additive in aqueous zinc sulfate (ZnSO\n                    <jats:sub>4<\/jats:sub>\n                    ) electrolytes. BTA modifies the electric double layer (EDL) structure on the Zn anode, alleviating the mismatch between Zn\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    mass transport and reduction kinetics. This leads to the formation of dense, flat zinc deposits rather than the Zn pulverized structures, significantly reducing contact loss during stripping. On the other hand, the strong chemisorption of BTA on the Cu substrate effectively blocks electron transfer pathways responsible for galvanic corrosion, reducing capacity fade during calendar aging. When paired with a MnO\n                    <jats:sub>2<\/jats:sub>\n                    cathode, the lean\u2010Zn anode enables the full cell to retain 90.3% of its capacity over 600 cycles at a negative: positive (N:P) ratio of 3:1.\n                  <\/jats:p>","DOI":"10.1002\/advs.77731","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T04:36:17Z","timestamp":1789101377000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Regulation of Deep\u2010Cycling\u2010Induced Zn Pulverization and Resting Galvanic Corrosion in Practical Lean Zinc Anodes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6294-2955","authenticated-orcid":false,"given":"Jing","family":"Xu","sequence":"first","affiliation":[{"name":"Research Center of Grid Energy Storage and Battery Application School of Electrical and Information Engineering Zhengzhou University  Zhengzhou 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