{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T19:56:08Z","timestamp":1790798168822,"version":"4.1.0"},"reference-count":60,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    In Nickel ferrites a low oxygen reduction activity and poor stability represent a drawback in rechargeable zinc\u2010air battery technology. This contribution presents a strategy using self\u2010templating for fabricating a nanohybrid material composed of NiFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    nanocubes encapsulated in N, P\u2010doped carbon nanohorns (CNH). Benefiting from the efficient mass and electron transfer of such N, P\u2010doping, CNH provide a significant number of active sites preventing aggregation and dissolution of active ferrite components in the composite. Thus, the NiFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    @CNH\u2010N\u2010P nanohybrid catalyst exhibits a high half\u2010wave potential (0.79\u00a0V) and a low Tafel slope of 56.5\u00a0mV\/dec, following a four\u2010electron pathway for oxygen reduction (ORR). The NiFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    @CNH\u2010N\u2010P nanohybrid catalyst work in full\u2010cell zinc air battery configuration as bifunctional cathode catalyst in conjunction with a ZnO\/C composite anode. The maximum power density derived from polarization curves for ZAB based on NiFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    @CNH\u2010N\u2010P is 54\u00a0mW\/cm\n                    <jats:sup>2<\/jats:sup>\n                    and thus exceeds a benchmark catalyst composed of 20% Pt\/C+RuO\n                    <jats:sub>2<\/jats:sub>\n                    of 28 by 26\u00a0mW\/cm\n                    <jats:sup>2<\/jats:sup>\n                    . The assembled secondary ZAB can be cycled for more than 300 h in a galvanostatic charge\u2013discharge test. This work provides insight into the rational composition and morphology design, as well as full materials and electrochemical characterization, of an earth\u2010abundant electrocatalyst with efficient electrocatalytic activity.\n                  <\/jats:p>","DOI":"10.1002\/advs.77749","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T18:00:31Z","timestamp":1790532031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Nickelferrite on Pnictogen Functionalized Carbon Nanohorns. Bifunctional ORR and OER Catalysts in Rechargeable Zinc\u2010Air Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2281-1301","authenticated-orcid":false,"given":"Sudheer Kumar","family":"Yadav","sequence":"first","affiliation":[{"name":"Department of Chemistry Inorganic Chemistry Eduard\u2010Zintl\u2010Institut F\u00fcr Anorganische und Physikalische Chemie Technical University Darmstadt  Darmstadt Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0325-7827","authenticated-orcid":false,"given":"Vanessa","family":"Trouillet","sequence":"additional","affiliation":[{"name":"Institute For Applied Materials (IAM\u2010ESS) and Karlsruhe Nano Micro Facility (KNMFi) Karlsruhe Institute of Technology (KIT)  Eggenstein\u2010Leopoldshafen 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