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Herein, a conduction\u2010nucleation competition mechanism is proposed firstly, clarifying that lithium deposition is governed by the synergy of these three factors. Guided by this principle, a self\u2010adaptive gradient buffer layer composed of soft carbon and Mg\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    (SCMN) is designed. After lithiation, the buffer forms a continuous lithiophobic\/lithiophilic gradient and subsequently undergoes\n                    <jats:italic>in\u2010situ<\/jats:italic>\n                    conversion into highly ion\u2010conductive Li\n                    <jats:sub>3<\/jats:sub>\n                    N and highly electron\u2010conductive\/ lithiophilic Li\u2010C\/Li\u2010Mg alloys during electrochemical activation, enabling dynamic interface self\u2010optimization. The gradient structure creates a fast ion\u2013electron dual conduction network, guiding bottom\u2010top lithium deposition within the buffer layer without volume expansion. Consequently, the symmetric cells achieve stable cycling over 1600 h at 1.5 mA cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    and remain stable even under low stack pressure (15 MPa). The LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based full cells deliver ultra\u2010stable cycle with 98.5% capacity retention after 200 cycles at 0.1 C. Additionally, the full cells paired with high\u2010voltage LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    cathodes exhibit exceptional cycling stability at high loading (4.45 mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ). This work demonstrates a mechanism\u2010driven design paradigm toward high\u2010energy, long\u2010life ASSLMBs.\n                  <\/jats:p>","DOI":"10.1002\/advs.77775","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T18:00:31Z","timestamp":1790532031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Conduction\u2010Nucleation\u2010Competition\u2010Guided 3D Adaptive Gradient Buffer for Dendrite\u2010Free All\u2010Solid\u2010State Lithium Metal Batteries"],"prefix":"10.1002","author":[{"given":"Yaru","family":"Shi","sequence":"first","affiliation":[{"name":"School of Environmental and Chemical Engineering Shanghai University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Libin","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Environmental and Chemical Engineering Shanghai University  Shanghai 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