{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T19:58:05Z","timestamp":1790798285187,"version":"4.1.0"},"reference-count":58,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22505028"],"award-info":[{"award-number":["22505028"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Passive radiative cooling, which reflects solar irradiation while emitting heat through the atmospheric window, provides a sustainable solution for zero\u2010energy thermal management. Simultaneously achieving high solar reflectivity and infrared emissivity remains challenging since the structural parameters governing light scattering and thermal radiation are intrinsically coupled. A block copolymer composite (denoted SEDO) of polystyrene\u2010\n                    <jats:italic>block<\/jats:italic>\n                    \u2010poly(ethylene\u2010\n                    <jats:italic>ran<\/jats:italic>\n                    \u2010butylene)\u2010\n                    <jats:italic>block<\/jats:italic>\n                    \u2010polystyrene (SEBS) with 9,10\u2010dihydro\u20109\u2010oxa\u201010\u2010phosphaphenanthrene\u201010\u2010oxide (DOPO) was judiciously designed and architected through multiscale phase segregation to enable decoupled structure\u2010determined spectral regulation. Macroscopic phase segregation in SEDO endows three\u2010dimensionally interconnected porous skeleton that enhances broadband Mie scattering, resulting in a high solar reflectivity of 97.2%. Meanwhile, DOPO fillers that selectively located in the polystyrene domains introduce strong molecular vibrational absorption within the atmospheric window. The cylindrical microphase separation morphology enables an emissivity of 95.5% with only 5 vol% additive. Benefiting from this decoupled optical regulation, the composite achieves sub\u2010ambient cooling of \u223c8.1\u00b0C under clear\u2010sky conditions and \u223c6.3\u00b0C under cloudy conditions, while maintaining efficient heat dissipation under high heat flux. Combined with excellent mechanical flexibility, flame retardancy, and environmental stability, this multiscale phase segregation strategy provides a versatile platform for augmented radiative cooling in practical thermal\u2010management applications via crafting spatially deterministic block copolymer composites.\n                  <\/jats:p>","DOI":"10.1002\/advs.77913","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T18:00:31Z","timestamp":1790532031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Architected Spatially Deterministic Multiscale Phase Segregation in Block Copolymer Composites for Augmented Radiative Cooling"],"prefix":"10.1002","author":[{"given":"Mingxin","family":"Feng","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Jiangsu Optoelectronic Functional Materials and Engineering Research Center, Jiangsu Key Laboratory of Advanced Optical Functional Film Materials and Technologies Southeast University Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feiyang","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Energy and Environment Southeast University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoran","family":"Cai","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Jiangsu Optoelectronic Functional Materials and Engineering Research Center, Jiangsu Key Laboratory of Advanced Optical Functional Film Materials and Technologies Southeast University Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenchao","family":"Zhai","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Jiangsu Optoelectronic Functional Materials and Engineering Research Center, Jiangsu Key Laboratory of Advanced Optical Functional Film Materials and Technologies Southeast University Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuangjiang","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Energy and Environment Southeast University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanmei","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering Nanjing University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohai","family":"Bu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering, Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology Nanjing Institute of Technology Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4535-8068","authenticated-orcid":false,"given":"Man","family":"He","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Jiangsu Optoelectronic Functional Materials and Engineering Research Center, Jiangsu Key Laboratory of Advanced Optical Functional Film Materials and Technologies Southeast University Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2289-1313","authenticated-orcid":false,"given":"Dudong","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Energy and Environment Southeast University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0457-5819","authenticated-orcid":false,"given":"Shuang","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Jiangsu Optoelectronic Functional Materials and Engineering Research Center, Jiangsu Key Laboratory of Advanced Optical Functional Film Materials and Technologies Southeast University Nanjing China"},{"name":"School of Materials Science and Engineering, Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology Nanjing Institute of Technology Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3506-3517","authenticated-orcid":false,"given":"Yuming","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Jiangsu Optoelectronic Functional Materials and Engineering Research Center, Jiangsu Key Laboratory of Advanced Optical Functional Film Materials and Technologies Southeast University Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,27]]},"reference":[{"key":"e_1_2_9_2_1","article-title":"Beyond Conventional Cooling: Advanced Micro\/Nanostructures for Managing Extreme Heat Flux","volume":"38","author":"Zhang Y.","year":"2025","journal-title":"Advanced Materials"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2025.12.026"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2025.102214"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.device.2024.100684"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwac208"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2024.101276"},{"key":"e_1_2_9_8_1","article-title":"Pushing Radiative Cooling Technology to Real Applications","volume":"37","author":"Lin C.","year":"2024","journal-title":"Advanced Materials"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401577"},{"key":"e_1_2_9_10_1","article-title":"Radiative Cooling Applications toward Enhanced Energy Efficiency: System Designs, Achievements, and Perspectives","volume":"6","author":"Chen H.","year":"2025","journal-title":"Innovation"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2025.115428"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2025.102321"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c06809"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.applthermaleng.2024.124310"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solmat.2024.112733"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solmat.2021.111129"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201069045\u20104"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adl0653"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45095-4"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-57366-9"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202518322"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41377\u2010023\u201001119\u20100"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302844"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48150-2"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1186\/s43074-025-00198-z"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1186\/s43593-023-00053-3"},{"key":"e_1_2_9_27_1","article-title":"Entropy\u2010Driven Multiphase Engineering Enables Superior Broadband Infrared Emissivity in High\u2010Entropy Oxides","volume":"38","author":"Wang C.","year":"2025","journal-title":"Advanced Materials"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513910"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010026\u201002039\u20100"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202400745"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202511138"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2024.08.020"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202207414"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202510053"},{"key":"e_1_2_9_35_1","article-title":"Articular Cartilage Inspired Ultra\u2010Strong and Tough Bio\u2010Based Polyurethane Nanofiber Membranes","volume":"65","author":"Li X.","year":"2025","journal-title":"Angewandte Chemie, International Edition"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202510461"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202422487"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2026.103841"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.4c00194"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202517801"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2023.101738"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202500958"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.2c00484"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.5c00805"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.4c03136"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2024.109393"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202411449"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2024.124222"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202512289"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504150"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201067831\u20100"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.6c04344"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c16540"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2026.103210"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.74505"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-026-71966-z"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202516139"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compositesb.2024.111362"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compositesb.2024.111947"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.77913","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.77913","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.77913","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T19:16:47Z","timestamp":1790795807000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.77913"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,27]]},"references-count":58,"alternative-id":["10.1002\/advs.77913"],"URL":"https:\/\/doi.org\/10.1002\/advs.77913","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,27]]},"assertion":[{"value":"2026-07-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-15","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-27","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e77913"}}