{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T16:10:56Z","timestamp":1790784656531,"version":"4.1.0"},"reference-count":49,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003704","name":"Korea Research Institute of Chemical Technology","doi-asserted-by":"publisher","award":["KS2622\u201040"],"award-info":[{"award-number":["KS2622\u201040"]}],"id":[{"id":"10.13039\/501100003704","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Sodium (Na) metal anodes are attracting great attention as next\u2010generation energy storage systems due to their high theoretical capacity, abundant resources, and low cost. However, an unstable solid\u2010electrolyte interphase (SEI), uncontrolled dendrite growth, and large volume changes are major factors limiting the practical application of Na metal anodes. Herein, we develop a Na\u2010Sb alloy anode featuring a three\u2010dimensional sodiophilic Na\n                    <jats:sub>3<\/jats:sub>\n                    Sb framework embedded within a metallic Na matrix. The interconnected Na\n                    <jats:sub>3<\/jats:sub>\n                    Sb framework homogenizes the Na\n                    <jats:sup>+<\/jats:sup>\n                    flux and provides abundant Na nucleation sites, enabling uniform Na deposition while effectively suppressing dendrite growth. Moreover, the engineered interface promotes the formation of a dense, NaF\u2010rich inorganic SEI with high mechanical strength and chemical stability, which effectively accommodates volume changes and stabilizes the Na metal\/electrolyte interface during repeated cycling. Consequently, the NSF\u20103||NSF\u20103 symmetric cell delivers remarkably stable cycling for over 1000\u00a0h at 0.5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with a capacity of 0.5 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , exhibiting significantly improved interfacial stability and Na plating behavior. This work demonstrates that constructing a sodiophilic Na\n                    <jats:sub>3<\/jats:sub>\n                    Sb framework is an effective strategy for regulating Na deposition and stabilizing the Na metal interface, providing a practical pathway toward high\u2010energy\u2010density and long\u2010life sodium metal batteries.\n                  <\/jats:p>","DOI":"10.1002\/advs.77935","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T18:00:31Z","timestamp":1790532031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Sodiophilic Na\n                    <sub>3<\/sub>\n                    Sb Framework\u2010Regulated Sodium Deposition and Interphase Evolution for Dendrite\u2010Free and Long\u2010Life Sodium Metal Batteries"],"prefix":"10.1002","author":[{"given":"So Hyun","family":"Lee","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Gyeongsang National University (GNU)  Jinju Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dawon","family":"Baek","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering and Convergence Technology Gyeongsang National University (GNU)  Jinju Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5715-8253","authenticated-orcid":false,"given":"Inkyung","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sang Jun","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering and Convergence Technology Gyeongsang National University (GNU)  Jinju Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3684-9829","authenticated-orcid":false,"given":"Ho Jin","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Advanced Materials Engineering Kyonggi University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tae Hoon","family":"Hwang","sequence":"additional","affiliation":[{"name":"Battery Development Center \u2013 Battery Electrode System Research Lab Hyundai Motor Company Co., Ltd Uiwang Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0452-9035","authenticated-orcid":false,"given":"San","family":"Moon","sequence":"additional","affiliation":[{"name":"Department of Advanced Battery Research Center Korea Research Institute of Chemical Technology (KRICT) Daejeon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4247-2850","authenticated-orcid":false,"given":"Joo\u2010Hyung","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Gyeongsang National University (GNU)  Jinju Republic of Korea"},{"name":"Department of Materials Engineering and Convergence Technology Gyeongsang National University (GNU)  Jinju Republic of 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