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Herein, two carbazole\u2010derived metal\u2010organic cages (MOCs) were constructed through coordination\u2010driven self\u2010assembly and subsequently transformed into fibrous metallogels (\n                    <jats:bold>MOC1G<\/jats:bold>\n                    and\n                    <jats:bold>MOC2G<\/jats:bold>\n                    ) in mixed DMSO\/H\n                    <jats:sub>2<\/jats:sub>\n                    O media through cooperative\n                    <jats:italic>\u03c0\u2212\u03c0<\/jats:italic>\n                    stacking and dynamic supramolecular interactions. The resulting metallogels display reversible gel\u2212sol transitions, interconnected nanofibrous architectures, and pronounced viscoelastic behavior. Rheological analyses revealed dominant elastic characteristics with rapid recovery after large mechanical deformation. Remarkably, the metallogels exhibit autonomous self\u2010healing without external stimuli, restoring their structural integrity within \u223c18\u00a0min for\n                    <jats:bold>MOC1G<\/jats:bold>\n                    and \u223c14\u00a0min for\n                    <jats:bold>MOC2G<\/jats:bold>\n                    after mechanical damage. Temperature\u2010dependent DLS and DSC studies further confirmed reversible thermally driven assembly\u2212disassembly processes. Beyond their adaptive soft\u2010matter properties, the discrete MOCs demonstrated highly efficient capture of iodine species from aqueous media, achieving uptake capacities up to 3.01\u00a0g g\n                    <jats:sup>\u20121<\/jats:sup>\n                    together with excellent selectivity and fast adsorption kinetics under both static and continuous\u2010flow conditions. In addition, the cages function as visible\u2010light\u2010responsive heterogeneous photocatalysts for aerobic sulfide oxidation, affording sulfoxides under mild conditions. This work establishes the first example of cage\u2010based metallogels that exhibit adaptive and autonomous self\u2010healing behavior while integrating environmental remediation and photocatalytic functionality within a single supramolecular platform.\n                  <\/jats:p>","DOI":"10.1002\/advs.78042","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T05:22:32Z","timestamp":1790745752000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Self\u2010Healing Pd(II) Cage Metallogels for Iodine Capture in Water and Heterogeneous Photocatalysis"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-6205-0683","authenticated-orcid":false,"given":"Monotosh","family":"Dalapati","sequence":"first","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER)  Bhubaneswar Odisha India"},{"name":"Homi Bhabha National 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