{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T08:50:04Z","timestamp":1791363004883,"version":"4.3.1"},"reference-count":56,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Ultrafast aqueous alkaline batteries (AABs) require anodes capable of sustaining rapid multielectron redox kinetics under extreme current densities. Although bismuth oxides offer high theoretical capacities, their high\u2010rate performance is constrained by the large nucleation barrier during phase transitions. This kinetic barrier remains unresolved by conventional charge\u2010transport engineering. Herein, one\u2010dimensional heterointerface\u2010seeded Bi\/Bi\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    @C nanowires are developed to regulate the phase\u2010transition pathway. Ex situ\/operando characterizations and theoretical analyses reveal that persistently retained Bi\/Bi\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    heterointerfaces serve as pre\u2010existing nucleation sites, enabling bidirectional Bi\n                    <jats:sup>0<\/jats:sup>\n                    \/Bi\n                    <jats:sup>3+<\/jats:sup>\n                    conversion via interfacial regrowth rather than repeated homogeneous nucleation. This seeded conversion pathway substantially reduces phase\u2010transition polarization, while the nitrogen\u2010doped carbon shell provides continuous electron\/OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    transport pathways and suppresses structural degradation. Consequently, the Bi\/Bi\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    @C anode delivers a specific capacity of 295.7 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and maintains 123.1 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    even at 150 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , alongside a capacity retention of 82.4% after 1000 cycles at 100 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This robust rate capability is preserved even at a high mass loading of 12.4\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Full AAB cells paired with a CoOOH\/Co(OH)\n                    <jats:sub>2<\/jats:sub>\n                    \/CoO cathode further demonstrate the device\u2010level feasibility of the proposed architecture. This heterointerface\u2010seeding strategy offers a general design principle for high\u2010capacity electrode materials operating under ultrafast\u2010charging conditions.\n                  <\/jats:p>","DOI":"10.1002\/advs.78066","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T14:44:11Z","timestamp":1790779451000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Heterointerface Seeding Accelerates Bi\n                    <sup>0<\/sup>\n                    \/Bi\n                    <sup>3+<\/sup>\n                    Phase Conversion for Ultrafast Aqueous Alkaline Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-2977-2006","authenticated-orcid":false,"given":"Jingwen","family":"Ma","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Shaanxi University of Technology  Hanzhong Shaanxi 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