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Here, we report a stepwise phase transition strategy that enables the formation of large\u2010area MOF glass membranes. By constructing a crystalline\u2010amorphous composite precursor, this strategy mitigates electrostatic repulsion and leverage graded viscoelastic flow to promote early\u2010stage interparticle bonding. This approach effectively suppresses cracking and pinhole defect formation during large\u2010area processing, providing a viable pathway toward scalable glassy membrane manufacturing. Based on this method, a record\u2010breaking 100 cm\n                    <jats:sup>2<\/jats:sup>\n                    MOF glass membrane exhibiting a CH\n                    <jats:sub>4<\/jats:sub>\n                    permeance of \u223c13,000 GPU and CH\n                    <jats:sub>4<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    selectivity of \u223c4.4, alongside a validated disc\u2010type module, has been successfully fabricated. This strategy establishes a scalable route for producing large\u2010area MOF glass membranes and advances their application in real\u2010world gas separation scenarios.\n                  <\/jats:p>","DOI":"10.1002\/advs.78073","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T04:47:50Z","timestamp":1790743670000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Scalable Fabrication of MOF Glass Membranes for Gas Separation via Stepwise Phase Transition"],"prefix":"10.1002","author":[{"given":"Mao","family":"Ye","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials Tiangong University  Tianjin China"},{"name":"School of Textile Science and Engineering Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Yang","sequence":"additional","affiliation":[{"name":"School of 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