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However, their application is blocked by the shuttle effect of polyiodide in the I\n                    <jats:sub>2<\/jats:sub>\n                    cathode and dendrite formation\/side reactions in the Zn metal anode. Here, a dual\u2010network hydrogel electrolyte consisting of polyacrylamide (PAM), chitosan (CS), and 2D vermiculite nanosheet (VN) is designed as PAM\/CS\/VN (PCV) to simultaneously address issues in the I\n                    <jats:sub>2<\/jats:sub>\n                    cathode and Zn metal anode. The 3D PCV network and 2D VN synergistically suppress the shuttle effect through physical confinement and strong adsorption. Hydrophilic\/zincophilic groups in PCV reduce free\u2010water activity and promote uniform Zn deposition, while electronegative VN sites coordinate Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , lowering the desolvation barrier and inhibiting dendrite formation. Under the regulation of multifunctional PCV, Zn||Zn symmetric batteries work for over 1100 h at 5 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and Zn\u2013I\n                    <jats:sub>2<\/jats:sub>\n                    batteries achieve a capacity retention of 97.4% after 10\u00a0000 cycles at 2 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The pouch battery delivers a capacity retention of 89.3% after 400 cycles at 0.5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This novel electrolyte and its effective additive offer valuable insights into enhancing the stable operation of Zn\u2013I\n                    <jats:sub>2<\/jats:sub>\n                    batteries.\n                  <\/jats:p>","DOI":"10.1002\/advs.78083","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T04:18:09Z","timestamp":1790655489000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["2D Vermiculite Nanosheets Encapsulated in Hydrogel Electrolyte for Shuttle\u2010Free and Dendrite\u2010Inhibited Zinc\u2010Iodine Batteries"],"prefix":"10.1002","author":[{"given":"Yunlong","family":"Zhou","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Hefei University of Technology  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanliang","family":"Wei","sequence":"additional","affiliation":[{"name":"School of 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