{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T03:50:51Z","timestamp":1791517851236,"version":"4.3.4"},"reference-count":46,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100020595","name":"National Science and Technology Council","doi-asserted-by":"publisher","award":["112\u20102113\u2010M\u2010001\u2010040\u2010MY3,114\u20102124\u2010M\u2010001\u2010016,115\u20102923\u2010M\u2010001\u2010003\u2010MY2,114\u20102628\u2010E\u2010011\u2010003\u2010MY3"],"award-info":[{"award-number":["112\u20102113\u2010M\u2010001\u2010040\u2010MY3,114\u20102124\u2010M\u2010001\u2010016,115\u20102923\u2010M\u2010001\u2010003\u2010MY2,114\u20102628\u2010E\u2010011\u2010003\u2010MY3"]}],"id":[{"id":"10.13039\/100020595","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001869","name":"Academia Sinica","doi-asserted-by":"publisher","award":["As\u2010GCP\u2010115\u2010M03"],"award-info":[{"award-number":["As\u2010GCP\u2010115\u2010M03"]}],"id":[{"id":"10.13039\/501100001869","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Achieving a homogeneous ion\u2010conducting network with sufficient mechanical strength and interfacial stability in Succinonitrile (SN)\u2010polyethylene oxide (PEO)\u2010based solid polymer electrolytes remains challenging. In particular, the temperature\u2010dependent interfacial behavior of SN in PEO\u2012lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) electrolytes is largely unexplored. Here, we reveal that SN undergoes temperature\u2010driven interfacial reactions at both lithium metal and cathodes, in addition to reactions involving PEO and LiTFSI. Notably, cathode\u2010side reactions contribute more to interfacial degradation and capacity fading than the widely studied lithium\u2010SN interfacial reactions. To address these challenges, a dual\u2010sided protection strategy using PEDOT\u2010based interfacial layers is developed. A PEO\u2012SN\u2012LiTFSI solid\u2010polymer electrolyte with high SN content and moderate salt concentration is reinforced with a poly(vinylidene fluoride\u2010co\u2010hexafluoropropylene) nanofiber network to maintain mechanical integrity and continuous ion\u2010conducting pathways. On the anode side, a PEDOT\u2010based nanofibrous mat coated with a thin gel layer suppresses the transport of reactive electrolyte species toward the lithium interface. On the cathode side, sulfonate\u2010functionalized PEDOT forms a conformal coating that suppresses interfacial reactions, including those associated with SN. This integrated design enables stable cycling for over 500 cycles and retains &gt;70% capacity at 50\u00b0C, demonstrating an effective strategy to suppress temperature\u2010driven interfacial reactions and achieve stable wide\u2010temperature (10\u00b0C\u201350\u00b0C) solid\u2010state battery operation.<\/jats:p>","DOI":"10.1002\/advs.78096","type":"journal-article","created":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T03:29:38Z","timestamp":1791516578000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Revealing Temperature\u2010Driven Interfacial Reactions of Succinonitrile in PEO\u2012LiTFSI Electrolytes and Suppressing Them via Dual PEDOT\u2010Based Interfacial Layers"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-7317-3269","authenticated-orcid":false,"given":"Baskar","family":"Selvaraj","sequence":"first","affiliation":[{"name":"Smart Organic Materials Laboratory Institute of Chemistry, Academia Sinica  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7622-8277","authenticated-orcid":false,"given":"Hailemichael","family":"Ayalew","sequence":"additional","affiliation":[{"name":"Smart Organic Materials Laboratory Institute of Chemistry, Academia Sinica  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Yao","family":"Tsai","sequence":"additional","affiliation":[{"name":"Smart Organic Materials Laboratory Institute of Chemistry, Academia Sinica  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ly Tho","family":"Xuan","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering National Taiwan University of Science and Technology  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Wei","family":"She","sequence":"additional","affiliation":[{"name":"Smart Organic Materials Laboratory Institute of Chemistry, Academia Sinica  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao\u2010Wen","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering National Taiwan University  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming\u2010Chou","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Central University  Taoyuan Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2072-1844","authenticated-orcid":false,"given":"Yu\u2010Sheng","family":"Hsiao","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering National Taiwan University of Science and Technology  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6545-8790","authenticated-orcid":false,"given":"Nae\u2010Lih","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering National Taiwan University  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3603-6932","authenticated-orcid":false,"given":"Hsiao\u2010hua","family":"Yu","sequence":"additional","affiliation":[{"name":"Smart Organic Materials Laboratory Institute of Chemistry, Academia Sinica  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521\u20104095(200107)13:12\/13<957::AID\u2010ADMA957>3.0.CO;2\u2010"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167\u20102738(03)00208\u2010X"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat1158"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp809465u"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2007.06.103"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c19260"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2781305"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301746"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202300892"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702184"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2006.08.017"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200601070"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee03025j"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201500353"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201901036"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.126754"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12367"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202310957"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202413205"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma3008509"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007172"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CP00735B"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep12967"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201904152"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201009924\u20101"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2007.12.047"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2009.08.087"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EB00153F"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b02690"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA03542B"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b07431"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2017.06.037"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b08200"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b02396"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.201801785"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100387\u20101"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202107326"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/aesr.202100088"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.10.024"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c04897"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202412003"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE03027A"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ04273C"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201606190"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5EE03764F"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c08487"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.78096","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.78096","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.78096","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T03:29:42Z","timestamp":1791516582000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.78096"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,8]]},"references-count":46,"alternative-id":["10.1002\/advs.78096"],"URL":"https:\/\/doi.org\/10.1002\/advs.78096","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,8]]},"assertion":[{"value":"2026-07-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-23","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e78096"}}