{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T16:52:53Z","timestamp":1791132773841,"version":"4.1.0"},"reference-count":80,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T00:00:00Z","timestamp":1791072000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T00:00:00Z","timestamp":1791072000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100022829","name":"Triad National Security","doi-asserted-by":"publisher","award":["89233218CNA000001"],"award-info":[{"award-number":["89233218CNA000001"]}],"id":[{"id":"10.13039\/100022829","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["2020LANLE372"],"award-info":[{"award-number":["2020LANLE372"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE\u2010AC52\u201006NA25396"],"award-info":[{"award-number":["DE\u2010AC52\u201006NA25396"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007000","name":"Laboratory Directed Research and Development","doi-asserted-by":"publisher","award":["20240286ER"],"award-info":[{"award-number":["20240286ER"]}],"id":[{"id":"10.13039\/100007000","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100019545","name":"Glenn T. Seaborg Institute","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100019545","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"ABSTRACT<\/jats:title>\n \n 13<\/jats:sup>\n C\u2010 and\n 2<\/jats:sup>\n H\u2010enriched bis((3,5\u2010dimethylphenyl)aminomethyl)\n \n tert<\/jats:sup>\n <\/jats:italic>\n butylphosphine (the natural abundance (NA) ligand\n \n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n <\/jats:bold>\n ; the\n 2<\/jats:sup>\n H\u2010 and\n 13<\/jats:sup>\n C\u2010labelled analogues are denoted as\n \n d<\/jats:italic>\n 4<\/jats:sub>\n \u2010\n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n <\/jats:bold>\n and\n \n 13<\/jats:sup>\n C\n 2<\/jats:sub>\n \u2010\n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n <\/jats:bold>\n , respectively), containing two secondary amines and a tertiary phosphine, was synthesized using a Kabachnik\u2013Fields protocol. The coordination chemistry of the ligand isotopologues (including the NA derivative) was investigated with the paramagnetic lanthanides Ce and Nd and the paramagnetic actinide elements Np and Pu, furnishing\n \n MI(\n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n )(thf)\n 3<\/jats:sub>\n <\/jats:bold>\n (M = Ce(\n 1<\/jats:bold>\n ), Nd(\n 2<\/jats:bold>\n ), Np(\n 3<\/jats:bold>\n ), Pu(\n 4<\/jats:bold>\n )),\n \n MI(\n d<\/jats:italic>\n 4<\/jats:sub>\n \u2010\n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n )(thf)\n 3<\/jats:sub>\n <\/jats:bold>\n (M = Ce(\n \n 2<\/jats:sup>\n H\u20101\n <\/jats:bold>\n ), Nd(\n \n 2<\/jats:sup>\n H\u20102\n <\/jats:bold>\n )) and\n \n MI(\n 13<\/jats:sup>\n C\n 2<\/jats:sub>\n \u2010\n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n )(thf)\n 3<\/jats:sub>\n <\/jats:bold>\n (M = Ce(\n \n 13<\/jats:sup>\n C\u20101\n <\/jats:bold>\n ), Nd(\n \n 13<\/jats:sup>\n C\u20102\n <\/jats:bold>\n ), Np(\n \n 13<\/jats:sup>\n C\u20103\n <\/jats:bold>\n ), Pu(\n \n 13<\/jats:sup>\n C\u20104\n <\/jats:bold>\n )); each complex bears the metal in the 3+ oxidation state chelated by the amide groups and phosphorus atom of the\n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n ligand. Multinuclear (\n 1<\/jats:sup>\n H,\n 31<\/jats:sup>\n P,\n 13<\/jats:sup>\n C, and\n 2<\/jats:sup>\n H) NMR characterization of the complexes revealed wide windows of paramagnetically shifted resonances; the isotopically enriched derivatives allowed for the unambiguous identification of the methylene environments, highlighting the utility of the\n \n Ar<\/jats:sup>\n BiAMP\n \n t<\/jats:sup>\n <\/jats:italic>\n Bu<\/jats:sup>\n <\/jats:bold>\n ligands for providing rich spectroscopic signatures of paramagnetic\n f<\/jats:italic>\n \u2010element coordination complexes. A combination of single\u2010crystal X\u2010ray diffraction and UV\u2010vis\u2010NIR spectroscopic techniques was also employed for the characterization of the compounds. Actinide complexes\n 3<\/jats:bold>\n and\n 4<\/jats:bold>\n possess rare examples of molecular transuranium element\u2013phosphorus bonds and the first examples of transuranium element\u2013phosphine interactions.\n <\/jats:p>","DOI":"10.1002\/advs.78113","type":"journal-article","created":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T16:14:17Z","timestamp":1791130457000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Phosphine Coordination to Ce, Nd, Np, and Pu in\n Ar<\/sup>\n BiAMP\n \n t<\/sup>\n <\/i>\n Bu<\/sup>\n \u2010Supported Complexes and Their\n 2<\/sup>\n H and\n 13<\/sup>\n C Isotopologues"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3607-4063","authenticated-orcid":false,"given":"Novan A. 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Additional synthetic and spectroscopic data will be presented and discussed in a future report."},{"key":"e_1_2_9_69_1","unstructured":"The 6\u2010coordinate ionic radii were used as there is no consistent set of 7\u2010coordinate radii reported for the f\u2010elements discussed in this work."},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50169a002"},{"key":"e_1_2_9_71_1","volume-title":"SHAPE, Program for the Stereochemical Analysis of Molecular Fragments by Means of Continuous Shape Measures and Associated Tools","author":"Llunell M.","year":"2013"},{"key":"e_1_2_9_72_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI00810C"},{"key":"e_1_2_9_73_1","unstructured":"Deposition numbers 2527016 (for P2N2) 2527017 (for 1) 2527018 (for 2) 2527019 (for 3) 2527020 (for 4) 2527021 (for PrI(ArBiAMPtBu)(thf)3) 2527022 (for TmI(ArBiAMPtBu)(thf)3) contain the supplementary crystallographic data for this paper. 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