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Multi\u2010target sensing scenarios often necessitate large\u2010scale sensor arrays, which inevitably increase the fabrication complexity, complicate visual interpretation, and exacerbate data redundancy. Here, we present a biomimetic photonic\u2010gustatory chip (BiPC) comprising a polyacrylate\u2010based solvatochromic disk (PSD) array. The elastic photonic crystal PSDs generate distinct color patterns when swelled by organic solvents. To fully unlock the sensing potential, a Hansen solubility parameter (HSP) framework was developed to assess the overall swelling cross\u2010reactivity toward target liquids, facilitating the design of a compact PSD array with HSP\u2010guided chemical diversity and maximized inter\u2010solvent response distinctiveness. Using intuitive pattern recognition, an HSP\u2010optimized four\u2010PSD array effectively differentiates solvent types and mixing ratios, homologues and isomers, as well as alcoholic beverages. Furthermore, we developed a smartphone application that integrated image capture with deep\u2010learning\u2010assisted cloud computing for on\u2010site solvent identification, achieving high accuracy (97.1% across 80 liquid classes) within 30 s. The HSP framework is generalizable to the design of compact sensor arrays for various field\u2010deployable liquid sensing scenarios.<\/jats:p>","DOI":"10.1002\/advs.78158","type":"journal-article","created":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T03:58:48Z","timestamp":1791518328000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Biomimetic Solvatochromic Chip With Optimized Chemical Diversity for On\u2010Site Liquid Identification"],"prefix":"10.1002","author":[{"given":"Jintao","family":"Zhang","sequence":"first","affiliation":[{"name":"The State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-1728-6264","authenticated-orcid":false,"given":"Hao","family":"Ouyang","sequence":"additional","affiliation":[{"name":"The State Key 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