{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T04:48:54Z","timestamp":1791866934458,"version":"4.3.4"},"reference-count":89,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    This study investigates continuous extruder mixing and high\u2011shear batch mixing to promote the formation of core\u2013shell\u2010like particle coatings for enhanced interfacial contact in dry\u2011coated sulfidic all\u2011solid\u2011state battery cathodes containing 82\u00a0wt.% high\u2010Ni NCM85 (LiNi\n                    <jats:sub>0.85<\/jats:sub>\n                    Co\n                    <jats:sub>0.10<\/jats:sub>\n                    Mn\n                    <jats:sub>0.05<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    , particle size D\n                    <jats:sub>50<\/jats:sub>\n                    3.8 \u00b5m) cathode active material and 0.5\u00a0wt.% polytetrafluoroethylene (PTFE) binder. Particle morphology and electrode microstructure are analyzed by particle size measurements, electron microscopy, and X\u2010ray characterization. Morphological observations indicate that extrusion yields a robust PTFE fibril network and a more homogeneous electrode surface, where deformed Li\n                    <jats:sub>6<\/jats:sub>\n                    PS\n                    <jats:sub>5<\/jats:sub>\n                    Cl solid electrolyte particles suggest a core\u2013shell\u2010like coating. Batch mixing resulted in reduced electrode quality, tensile strength, and microstructure homogeneity. Despite its dedicated mechanofusion process and higher specific mechanical energy input (\u223c speed, time), a distinct core\u2013shell\u2010like coating is not evident for such a small\u2010particle system. Charge transport features are analyzed in symmetric cells under blocking conditions. Batch\u2011mixed electrodes attain higher electronic conductivity, whereas extruder\u2011mixed electrodes achieve higher ionic conductivity. These differences likely arise from microstructural features. Electrochemical characterization of half\u2011cells demonstrates the enhanced performance of extruder\u2011mixed electrodes, including higher active material utilization, reduced overpotentials, and improved rate capability. Overall, extruder mixing provides a scalable and effective route for engineering the electrode microstructure.\n                  <\/jats:p>","DOI":"10.1002\/advs.78248","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T04:31:56Z","timestamp":1791865916000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Microstructure Evolution in Dry\u2011Coated Sulfidic All\u2010Solid\u2010State Battery Cathodes: Investigating Core\u2013Shell Particle Morphology"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-6507-7768","authenticated-orcid":false,"given":"Michael","family":"Wolf","sequence":"first","affiliation":[{"name":"Institute of Business Chemistry University of M\u00fcnster, Leonardo Campus 1  M\u00fcnster Germany"},{"name":"Bayerische Motoren Werke AG  M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-8127-2314","authenticated-orcid":false,"given":"Aaron","family":"Stoeckle","sequence":"additional","affiliation":[{"name":"Bayerische Motoren Werke AG  M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4161-5197","authenticated-orcid":false,"given":"Rebecca","family":"Wilhelm","sequence":"additional","affiliation":[{"name":"TUM School of Natural Sciences Department of Chemistry and Catalysis Research Center Chair of Technical Electrochemistry Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6944-2136","authenticated-orcid":false,"given":"Maximilian A.","family":"Plass","sequence":"additional","affiliation":[{"name":"Bayerische Motoren Werke AG  M\u00fcnchen Germany"},{"name":"Max Planck Institute for Solid State Research  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