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Although this effect has been extensively demonstrated on densely packed nanostructures, the capability of microscale textures to support jumping condensation remains poorly understood. By systematically varying cone pitch within a series of microcone arrays with comparable cone geometries, we observe previously unreported spacing\u2010dependent transition between jumping and non\u2010jumping regimes. In the jumping regime, we identify a geometric threshold below which sub\u201010\u00a0\u00b5m droplets are rapidly removed, and above which jumping is suppressed, resulting in slower dynamics and larger departing droplets. In situ optical and environmental scanning electron microscopies provide evidence supporting a mechanistic interpretation of this transition: dense arrays favor full Cassie droplets, which depart cleanly, while wider spacing favors partial Cassie droplets that retain a localized wet region initiating new nucleation. Our findings establish a mechanistic link between the morphology of condensing microdroplets and the macroscopic jumping dynamics that govern performance in anti\u2010fogging, water harvesting, and heat\u2010transfer applications.<\/jats:p>","DOI":"10.1002\/advs.78273","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T03:49:59Z","timestamp":1792036199000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unlocking the Full Potential of Jumping Condensation on Microstructured Surfaces"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0676-2674","authenticated-orcid":false,"given":"Mariia S.","family":"Kiseleva","sequence":"first","affiliation":[{"name":"Department of Applied Physics Aalto University Espoo 02150 Finland"},{"name":"Centre of Excellence in Life\u2010Inspired Hybrid Materials (LIBER) Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8691-5898","authenticated-orcid":false,"given":"Tytti","family":"K\u00e4rki","sequence":"additional","affiliation":[{"name":"Department of Applied Physics Aalto University Espoo 02150 Finland"},{"name":"Centre of Excellence in Life\u2010Inspired Hybrid Materials (LIBER) Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mika","family":"Latikka","sequence":"additional","affiliation":[{"name":"Department of Applied Physics Aalto University Espoo 02150 Finland"},{"name":"Centre of Excellence in Life\u2010Inspired Hybrid Materials (LIBER) Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Parham","family":"Koochak","sequence":"additional","affiliation":[{"name":"Department of Applied Physics Aalto University Espoo 02150 Finland"},{"name":"Centre of Excellence in Life\u2010Inspired Hybrid Materials (LIBER) Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sakari","family":"Lepikko","sequence":"additional","affiliation":[{"name":"Department of Applied Physics Aalto University Espoo 02150 Finland"},{"name":"Centre of Excellence in Life\u2010Inspired Hybrid Materials (LIBER) Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5895-7612","authenticated-orcid":false,"given":"Maja","family":"Vuckovac","sequence":"additional","affiliation":[{"name":"Department of Applied Physics Aalto University Espoo 02150 Finland"},{"name":"Centre of Excellence in Life\u2010Inspired Hybrid Materials (LIBER) Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tomi","family":"Koskinen","sequence":"additional","affiliation":[{"name":"Department of Electronics and Nanoengineering Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1802-9077","authenticated-orcid":false,"given":"Ramesh","family":"Raju","sequence":"additional","affiliation":[{"name":"Department of Electronics and Nanoengineering Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6347-7461","authenticated-orcid":false,"given":"Ville P.","family":"Jokinen","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Materials Science Aalto University Espoo 02150 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8973-8719","authenticated-orcid":false,"given":"Jiazheng","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Mechanical Science and Engineering The Grainger College of Engineering University of Illinois Urbana\u2010Champaign Urbana Illinois USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0866-3680","authenticated-orcid":false,"given":"Nenad","family":"Miljkovic","sequence":"additional","affiliation":[{"name":"Department of Mechanical Science and Engineering The Grainger College of Engineering University of Illinois Urbana\u2010Champaign Urbana Illinois USA"},{"name":"Materials Research Laboratory University of Illinois Urbana\u2010Champaign Urbana Illinois USA"},{"name":"Department of Electrical and Computer Engineering University of Illinois Urbana\u2013Champaign Urbana Illinois USA"},{"name":"International Institute For Carbon Neutral Energy Research (WPI\u2010I2CNER) Kyushu University  Fukuoka Japan"},{"name":"Air Conditioning and Refrigeration Center Department of Mechanical Science and Engineering University of Illinois Urbana\u2010Champaign Urbana Illinois USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5499-1482","authenticated-orcid":false,"given":"Jaakko V. 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